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85033045706
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note
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isc.
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39
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85033048171
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Performed on molecular mechanics software, Macromodel.
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Macromodel
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-
-
40
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85033050114
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note
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2 carbons incorporated into an already strained system should further increase the strain energy content and result in the nonplanar chromophore suggested by the calculations.
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45
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0007664531
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0000895532
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(b) Based upon activation parameters reported within: Caldwell, R. A.; Misawa, H.; Healy, E. F.; Dewar, M. J. S. J. Am. Chem. Soc. 1987, 109, 6869.
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47
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85033053668
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note
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Usually a quenching rate constant is measured by adding enough quencher to change the decay kinetics by at least 1 full order of magnitude. This was not possible in this case due to the slow bimolecular rate constant and the initially fast decay kinetics of the trans-Ret-9 transient. The value reported must be considered a "ball-park" upper limit for the actual bimolecular rate constant.
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