Structures, Bonding, and Reactivity of M-S-M' (M and M' = Rh, W, and Cu) Groups in Higher-Nuclearity Heterometallic Sulfide Clusters

Inorganic Chemistry

Volumn 35, Issue 21, 1996, Pages 6093-6101

  Ogo, Seiji ^a   Suzuki, Takayoshi ^a,d   Ozawa, Yoshiki ^b   Isobe, Kiyoshi ^c  

^a GRADUATE UNIVERSITY FOR ADVANCED STUDIES   (Japan)

^b UNIVERSITY OF HYOGO   (Japan)

^c Osaka Prefecture University   (Japan)

^d OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000729087     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9601807     Document Type: Article

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44. Cu1-S4 = 2.291 Å. Cu1-S3 = 2.299 Å, Cu1-Cl1 = 2.332 Å, and Cu1-Cl1* = 2.387 Å. The distances between Cu1 and a centroid of the S3Cl1Cl1* plane (represented by Cu1-(S3Cl1Cl1*)) is 0.835 Å. Cu1-(S4Cl1Cl1*) = 0.787 Å, Cu1-(S3S4Cl1*) = 0.704 Å, and Cu1-(S3S4Cl1) = 0.735 Å.
45. 4- (M = W, Mo; see ref 12).
46. The distance between Cul and a centroid of the S1S3Cl1 plane (represented by Cu1-(S1S3Cl1)) is 0.323(1) Å. Cu2-(S2S3Cl2) is 0.092(2) Å.
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50. 2S immediately.
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61. 1,120,0.005 = 1.034.