Tetrahydrofuran Adducts of Bismuth Trichloride and Bismuth Tribromide

Inorganic Chemistry

Volumn 35, Issue 12, 1996, Pages 3709-3712

  Carmalt, Claire J ^a   Clegg, William ^a   Elsegood, Mark R J ^a   John Errington, R ^a   Havelock, Jeanne ^a   Lightfoot, Philip ^b   Norman, Nicholas C ^a,c   Scott, Andrew J ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

^b UNIVERSITY OF ST ANDREWS   (United Kingdom)

^c UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000716631     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951635f     Document Type: Article

References (19)

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11. In the structure of 1, the position of Br(1) is disordered, the minor component (labelled Br(1')) of about one-third occupancy having a Bi-Br distance of 2.685(10) Å. In considering the trend between the observed Bi-Br and Bi-O distances, it is the distance to the major component which has been used. Also, when considering the stereochemical influence of the Bi(III) lone pair, it is the major component to which the discussion refers; in the minor component, the lone pair may be slightly more stereochemically active.
12. Clegg, W.; Errington, R. J.; Fisher, G. A.; Hockless, D. C. R.; Norman, N. C.; Orpen, A. G.; Stratford, S. E. J. Chem. Soc., Dalton Trans. 1992, 1967.
13. Sobota, P.; Utko, J.; Szafert, S. Inorg. Chem. 1994, 33, 5203.
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