Product studies of the OH- and ozone-initiated oxidation of some monoterpenes

Journal of Geophysical Research Atmospheres

Volumn 105, Issue D9, 2000, Pages 11561-11572

  Orlando, John J ^a   Nozière, Barbara ^b   Tyndall, Geoffrey S ^a   Orzechowska, Grazyna E ^c   Paulson, Suzanne E ^c   Rudich, Yinon ^d  

^a NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^b NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

MONOTERPENE; OXIDATION; OZONE;

EID: 0000707296     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2000JD900005     Document Type: Article

References (63)

1. 3 with α-pinene and 1,2-dimethyl-1-cyclohexene, J. Geophys. Res., 103, 25,541-25,551, 1998.
2. Andreae, M., and P. J. Crutzen, Atmospheric aerosols: Biogeochemical sources and role in atmospheric chemistry, Science, 276, 1052-1058, 1997.
3. Andreae, M., R. W. Talbot, T. W. Andreae, and R. C. Harriss, Formic and acetic acid over the central Amazon region, Brazil 1. Dry season, J. Geophys. Res., 93, 1616-1624, 1988.
4. x, J. Geophys. Res., 95, 18,539-18,546, 1990.
5. Aschmann, S. M., A. Reissell, R. Atkinson, and J. Arey, Products of the gas phase reactions of the OH radicals with α- and β-pinene in the presence of NO, J. Geophys. Res., 103, 25,553-25,562, 1998.
6. Atkinson, R., Gas-phase tropospheric chemistry of organic compounds, J. Phys. Chem. Ref. Data Monogr. 2, 1-216, 1997a.
7. Atkinson, R., Gas-phase tropospheric chemistry of volatile organic compounds: 1. Alkanes and alkenes, J. Phys. Chem. Ref. Data, 26, 215-290, 1997b.
8. Atkinson, R., Atmospheric reactions of alkoxy and β-hydroxyalkoxy radicals, Int. J. Chem. Kinet., 29, 99-111, 1997c.
9. 2 with alkenes and dialkenes, Int. J. Chem. Kinet., 16, 697-706, 1984.
10. Atkinson, R., S. M. Aschmann, J. Arey, and B. Shorees, Formation of OH radicals in the gas phase reactions of ozone with a series of terpenes, J. Geophys. Res., 97, 6065-6073, 1992.
11. Atkinson, R., E. C. Tuazon, and S. Aschmann, Products of the gas-phase reactions of a series of 1-alkenes and 1-methylcyclohexene with the OH radical in the presence of NO, Environ. Sci. Technol., 29, 1674-1680, 1995.
12. Atkinson, R., E. C. Tuazon, and S. Aschmann, Products of the gas-phase reaction of the OH radicals with 3-methyl-1-butene in the presence of NO, Int. J. Chem. Kinet., 30, 577-587, 1998.
13. Aumont, B., S. Madronich, I. Bey, and G. S. Tyndall, Contribution of secondary VOC to the composition of aqueous atmospheric particles: A modeling approach, J. Atm. Chem., 35, 59-75, 2000.
14. Biesenthal, T. A., J. W. Bottenheim, P. B. Shepson, S.-M. Li, and P. C. Brickell, The chemistry of biogenic hydrocarbons at a rural site in eastern Canada, J. Geophys. Res., 103, 25,487-25,498, 1998.
15. Calogirou, A., B. R. Larsen, and D. Kotzias, Gas-phase terpene oxidation products: A review, Atmos.Environ., 33, 1423-1439, 1999.
16. DeMore, W. B., S. P. Sander, D. M. Golden, R. F. Hampson, M. J. Kurylo, C. J. Howard, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, Evaluation No. 12, NASA JPL Publ. 97-4, 1997.
17. Fehsenfeld, F., et al., Emissions of volatile organic compounds from vegetation and the implications for atmospheric chemistry, Global Biogeochem. Cycles, 6, 389-430, 1992.
18. Goldan, P. D, W. C. Kuster, F. C. Fehsenfeld, and S. A. Montzka, Hydrocarbon measurements in the southeastern United States: The Rural Oxidants in the Southern Environment (ROSE) Program 1990, J. Geophys. Res, 100, 25,945-25,963, 1995.
19. Grosjean, D., E. L. Williams II, and J. H. Seinfeld, Atmospheric oxidation of selected terpenes and related carbonyls: Gas-phase carbonyl products, Environ. Sci. Technol., 26, 1526-1533, 1992.
20. Grosjean, D., E. L. Williams, E. Grosjean, J. M. Andino, and J. H. Seinfield, Atmospheric oxidation of biogenic hydrocarbons: reaction of ozone with β-pinene, Δ-limonene and trans-caryophyllene, Environ. Sci. Technol., 27, 2754-2758, 1993.
21. Gu, C. L., C. M. Rynard, D. G. Hendry, and T. Mill, OH radical oxidation of α-pinene, report to U.S. Environ. Prot. Agency, SRI Int., Menlo Park, CA, 1984.
22. Guenther, A., et al., A global model of natural volatile organic compound emissions, J. Geophys. Res., 100, 8873-8892, 1995.
23. Guenther, A., C. Geron, T. Pierce, B. Lamb, P. Harley, and R. Fall, Natural emissions of non-methane volatile organic compounds, CO and oxides of nitrogen from North America, Atmos. Environ., in press, 2000.
24. 3 with β-phellandrene, Environ. Sci. Technol., 27, 278-283, 1993.
25. 3 with a series of monoterpenes, J. Atmos. Chem., 18, 75-102, 1994.
26. Hakola, H., J. Rinne, and T. Laurila, The hydrocarbon emission rate of tea-leafed willow (Salixphylicifolia), silver birch (Betula pendula) and European aspen (Populus tremula), Atmos. Environ., 32, 1825-1833, 1998.
27. Hatakeyama, S., K. Izumi, T. Fukuyama, and H. Akimoto, Reactions of ozone with α-pinene and β-pinene in air: Yields of gaseous and particulate products, J. Geophys. Res., 94, 13,013-13,024, 1989.
28. Hatakeyama, S., K. Izumi, T. Fukuyama, H. Akimoto, and N. Washida, Reactions of OH with α-pinene and β-pinene in air: Estimate of global CO production from the atmospheric oxidation of terpenes, J. Geophys. Res., 96, 947-958, 1991.
29. Helmig, D., B. Balsley, K. Davis, L. R. Kuck, M. Jensen, J. Bognar, T. Smith Jr., R. V. Arrieta, R. Rodriguez, and J. W. Birks, Vertical profiling and determination of landscape fluxes of biogenic nonmethane hydrocarbons within the planetary boundary layer in the Peruvian Amazon, J. Geophys. Res., 103, 25,519-25,532, 1998a.
30. Helmig, D., J. Greenberg, A. Guenther, P. Zimmerman, and C. Geron, Volatile organic compounds and isoprene oxidation products at a temperate deciduous forest site, J. Geophys. Res., 103, 22,397-22,414, 1998b.
31. Helmig, D., L. F. Klinger, A. Guenther, L. Vierling, C. Geron, P. Zimmerman, Biogenic volatile organic compound emissions (BVOCs) I. Identifications from three continental sites in the U. S., Chemosphere, 38, 2163-2187, 1999a.
32. Helmig, D., L. F. Klinger, A. Guenther, L. Vierling, C. Geron, P. Zimmerman, Biogenic volatile organic compound emissions (BVOCs) II. Landscape flux potentials from three continental sites in the U. S., Chemosphere, 38, 2189-2204, 1999b.
33. Horner, J., N. Tanaka, and M. Newcomb, Kinetics of cyclopropylcarbinyl radical ring openings measured directly by laser flash photolysis, J. Am. Chem. Soc., 120, 10,379-10,390, 1998.
34. Jacob, D. J., and S. C. Wofsy, Photochemistry of biogenic emissions over the Amazon forest, J. Geophys. Res., 93, 1477-1486, 1988.
35. Kesselmeier, J., et al., Emission of short chained organic acids, aldehydes, and monoterpenes, from Quercus ilex L. and Pinus pinea L. in relation to physiological activities, carbon budget and emission algorithms, Atmos. Environ., 31, Suppl.1, S119-S133, 1997.
36. Kramp, F., and S. E. Paulson, The gas phase reaction of ozone with butadiene: Formation yields of some toxic products, Atmos. Environ., 34, 35-43, 2000.
37. Kwok, E. S. C., and R. Atkinson, Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: an update, Atmos. Environ., 29, 1685-1695, 1995.
38. Kwok, E. S. C., R. Atkinson, and J. Arey, Observation of hydroxycarbonyls from the OH radical-initiated reactions of isoprene, Environ. Sci. Technol., 29, 2467-2469, 1995.
39. 8 1-alkenes, Environ. Sci. Technol., 30, 1048-1052, 1996.
40. Makar, P. A., J. D. Fuentes, D. Wang, R. M. Staebler, and H. A. Wiebe, Chemical processing of biogenic hydrocarbons within and above a temperate deciduous forest, J. Geophys. Res., 104, 3581-3603, 1999.
41. Meagher, R. J., M. E. McIntosh, M. D. Hurley, and T. J. Wallington, A kinetic study of the reaction of chlorine and fluorine atoms with HCOF at 295 ± 2 K, Int. J. Chem. Kinet., 29, 619-625, 1997.
42. Newcomb, M., Competitive methods and scales for alkyl radical reaction kinetics, Tetrahedron, 49, 1151-1176, 1993.
43. Newcomb, M., S. Choi, and J. Horner, Adjusting the top end of the alkyl radical kinetic scale. Laser flash photolysis calibrations of fast radical clocks and rate constants for reactions of benzeneselenol, J. Org. Chem., 64, 1225-1231, 1999.
44. Nozière, B., I. Barnes, and K.-H. Becker, Product study and mechanisms of the reactions of α-pinene and of pinonaldehyde with OH radicals, J. Geophys. Res., 104, 23,645-23,656, 1999a.
45. Nozière, B., M. Spittler, L. Ruppert, I. Barnes, and K.-H. Becker, Kinetics of the reactions of pinonaldehyde with OH radicals and with CI atoms, Int. J. Chem. Kinet., 31, 291-301, 1999b.
46. x in the boundary layer, Geophys. Res. Lett., 23, 3727-3730, 1996.
47. Paulson, S. E., and J. H. Seinfeld, Development and evaluation of a photooxidation mechanism for isoprene, J. Geophys. Res., 97, 20,703-20,715, 1992.
48. Paulson, S. E., M. Chung, and G. Orzechowska, Measurement of OH radical formation from the reaction of ozone with several biogenic alkenes, J. Geophys. Res., 103, 25,533-25,539, 1998.
49. Peeters, J., W. Boullart, and J. Van Hoeymissen, Site-specific partial rate constants for OH addition to alkenes and dienes, in The Proceedings of EUROTRAC Symposium '94, edited by P. M. Borrell et al., PSB Academic, The Hague, Netherlands, pp. 100-114, 1994.
50. 3-initiated reactions of a series of monoterpenes, J. Geophys. Res., 104, 13,869-13,879, 1999.
51. Roselle, S. J., T. E. Pierce, and K. L. Schere, The sensitivity of regional ozone modeling to biogenic hydrocarbons, J. Geophys. Res., 96, 7371-7394, 1991.
52. Ruppert, L., et al., Product and aerosol formation from the ozonolysis of monoterpenes, paper presented at the Workshop on Biogenic Hydrocarbons in the Atmospheric Boundary Layer," American Meteorological Society, Charlottesville, VA, Aug. 1997.
53. Scanlon, J.T., and D. E. Willis, Calculation of flame ionization detector relative response factors using the effective carbon number concept, J. Chromatogr. Sci., 23, 333-340, 1985.
54. Seufert, G., et al., An overview of the Castelporziano experiments, Atmos. Environ., 31, Suppl. 1, S5-S17, 1997.
55. Shetter, R. E., J. A. Davidson, C. A. Cantrell, and J. G. Calvert, Temperature variable long path cell for absorption measurements, Rev. Sci. Instrum., 58, 1427-1428, 1987.
56. Singh, H. B., D. O'Hara, D. Herlth, W. Sachse, D. R. Blake, J. D. Bradshaw, M. Kanakidou, and P. J. Crutzen, Acetone in the atmosphere: Distribution, sources and sinks, J. Geophys. Res., 99, 1805-1819, 1994.
57. Singh, H. B., M. Kanakidou, P. J. Crutzen, and D. J. Jacob, High concentrations and photochemical fate of oxygenated hydrocarbons in the global troposphere, Nature, 378, 50-54, 1995.
58. Su, F., J. G. Calvert, and J. H. Shaw, Mechanism of the photooxidation of gaseous formaldehyde, J. Phys. Chem., 83, 3185-3191, 1979.
59. Talbot, R. W., M. O. Andreae, H. Berresheim, D. J. Jacob, and K. M. Beecher, Sources and sinks of formic, acetic, and pyruvic acids over central Amazonia 2. Wet season, J. Geophys. Res., 95, 16,799-16,811, 1990.
60. Taylor, W. D., T. D. Allston, M. J. Moscato, G. B. Fazekas, R. Kozlowski, and G. A. Takacs, Atmospheric photodissociation lifetimes for nitromethane, methyl nitrite, and methyl nitrate, Int. J. Chem. Kinet., 12, 231, 1980.
61. Trainer, M., et al., Models and observations of the impact of natural hydrocarbons on rural ozone, Nature, 329, 705-707, 1987.
62. Vereecken, L., J. Peeters, J. J. Orlando, G. S. Tyndall, and C. Ferronato, Decomposition of β-hydroxypropoxy radicals in the OH-initiated oxidation of propene: A theoretical and experimental study, J. Phys. Chem. A, 103, 4693-4702, 1999.
63. Zimmerman, P. R., J. P. Greenberg, and C. E. Westberg, Measurements of atmospheric hydrocarbons and biogenic emission fluxes in the Amazon boundary layer, J. Geophys. Res., 93, 1407-1416, 1988.