Iodine charge-transfer salts of benzene-bridged bis(1,2,3,5- diselenadiazolyl) diradicals. Electrocrystallization and solid-state characterization of 1,3- and 1,4-[(Se2N2C)C 6H4(CN2Se2)][I]

Chemistry of Materials

Volumn 8, Issue 3, 1996, Pages 762-768

  Bryan, C D ^a   Cordes, A W ^a   George, N A ^b   Haddon, R C ^c   MacKinnon, C D ^b   Oakley, R T ^b   Palstra, T T M ^c   Perel, A S ^c  

^a UNIVERSITY OF ARKANSAS   (United States)

^b UNIVERSITY OF GUELPH   (Canada)

^c LUCENT TECHNOLOGIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; CRYSTAL STRUCTURE; ELECTROLYTIC REDUCTION; ELECTRONIC STRUCTURE; SALTS; SELENIUM COMPOUNDS; SINGLE CRYSTALS;

BENZENE BRIDGED; CHARGE-TRANSFER SALTS; DIRADICALS; ELECTRO REDUCTION; ELECTROCRYSTALLIZATION; IODIDE/TRI-IODIDE; MONOCLINIC SPACE GROUPS; ORTHORHOMBIC SPACE GROUPS; SOLID STATE CHARACTERIZATION; SPACE GROUPS;

IODINE;

EID: 0000699426     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm950446s     Document Type: Article

References (30)

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21. The correspondence of the directions of the reciprocal and real-space vectors is exact for all the structures discussed save [1,4-Se][I]. In [1,4-Se][I] the discussion still retains qualitative value.
22. We note, however, that the anisotropies in the conductivity of [1,4-S][I] were suggestive of a relatively isotropic material.
23. 2: C, 22.98; H, 1.23; N, 7.31%. Found: C, 23.12; H, 1.24; N, 7.50%.
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26. 4I: C, 16.04; H, 0.67; N, 9.36; I, 21.19%. Found for [1,4-Se][I]: C, 15.98; H, 0.73; N, 9.12%; I, 21.41%. Found for [1,3-Se][I]: C, 15.90; H, 0.56; N, 9.16%. The iodine analysis for the latter compounds was variable and irreproducible, as a result of interference from selenium. Repeated and consistent C, H, and N data, plus the iodine occupancy from the X-ray work, confirmed the composition.
27. 4: I, 51.82%. Found: I, 51.98%.
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