Ruthenium Porphyrins Containing Nitrosyl, Nitrosamine, Thiolate, and Amine Ligands

Inorganic Chemistry

Volumn 35, Issue 12, 1996, Pages 3453-3454

  Yi, Geun Bae ^a   Khan, Masood A ^a   Richter Addo, George B ^a  

^a UNIVERSITY OF OKLAHOMA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000696521     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951600f     Document Type: Article

References (28)

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4. Richter-Addo, G. B., Legzdins, P. Metal Nitrosyls; Oxford University Press: New York, 1992; Chapter 6.
5. Yu, A. E.; Hu, S.; Spiro, T. G.; Burstyn, J. N. J. Am. Chem. Soc. 1994, 116, 4117.
6. Appel, K. E.; Ruf, H. H.; Mahr, B.; Schwarz, M.; Rickart, R.; Kunz, W. Chem.-Biol. Interact. 1979, 28, 17.
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11. (a) Hurshman, A. R.; Marietta, M. A. Biochemistry 1995, 34, 5627.
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13. Yi, G.-B.; Khan, M. A.; Richter-Addo, G. B. J. Am. Chem. Soc. 1995, 117, 7850.
14. Satisfactory analytical data (±0.4% for C, H, N, Cl) were obtained for the new complexes 2-7. Full synthesis and characterization details (NMR, IR, and mass spectral data; elemental analyses) are deposited as Supporting Information. OEP = octaethylporphyrinato dianion.
15. Other ruthenium nitrosyl porphyrins reported: (a) Srivastava, T. S.; Hoffman, L.; Tsutsui, M. J. Am. Chem. Soc. 1972, 94, 1385. (b) Massoudipour, M.; Pandey, K. K. Inorg. Chim. Acta 1989, 160, 115. (c) Antipas, A.; Buchler, J. W.; Gouterman, M.; Smith, P. D. J. Am. Chem. Soc. 1978, 100, 3015.
16. Other ruthenium nitrosyl porphyrins reported: (a) Srivastava, T. S.; Hoffman, L.; Tsutsui, M. J. Am. Chem. Soc. 1972, 94, 1385. (b) Massoudipour, M.; Pandey, K. K. Inorg. Chim. Acta 1989, 160, 115. (c) Antipas, A.; Buchler, J. W.; Gouterman, M.; Smith, P. D. J. Am. Chem. Soc. 1978, 100, 3015.
17. Other ruthenium nitrosyl porphyrins reported: (a) Srivastava, T. S.; Hoffman, L.; Tsutsui, M. J. Am. Chem. Soc. 1972, 94, 1385. (b) Massoudipour, M.; Pandey, K. K. Inorg. Chim. Acta 1989, 160, 115. (c) Antipas, A.; Buchler, J. W.; Gouterman, M.; Smith, P. D. J. Am. Chem. Soc. 1978, 100, 3015.
18. + (TPP = meso-tetraphenylporphyrinato dianion) has been described: Kadish, K. M.; Adamian, V. A.; Van Caemelbecke, E.; Tan, Z.; Tagliatesta, P.; Bianco, P.; Boschi, T.; Yi, G.-B.; Khan, M. A.; Richter-Addo, G. B. Inorg. Chem. 1996, 35, 1343.
19. + (100%).
20. - complexes have linear Fe-N-O linkages: Scheidt, W. R.; Lee, Y. J.; Hatano, K. J. Am. Chem. Soc. 1984, 106, 3191.
21. +(100%).
22. -1 regions, respectively: Williams, R. L.; Pace, R. J.; Jeacocke, G. J. Spectrochim. Acta 1964, 20, 225.
23. -1, respectively. However, this compound is prone to NO loss: Chen, L.; Yi, G.-B. Unpublished observations.
24. 18O: Keefer, L. K.; Hrabie, J. A.; Hilton, B. D.; Wilbur, D. J. Am. Chem. Soc. 1988, 110, 7459.
25. + (100%).
26. + (100%).
27. + (100%).
28. + (100%).