Synthesis and structure of the solvent-free sodium aryl (NaC6H3-2,6-Mes2)2

Organometallics

Volumn 16, Issue 15, 1997, Pages 3258-3260

  Niemeyer, Mark ^a   Power, Philip P ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000685256     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970247d     Document Type: Article

References (19)

1. See for example: Houben-Weyl. Methoden der Organischen Chemie; Thieme: Stuttgart, Germany, 1970; Vol. XIII 1. The synthesis of halide-free NaPh was first described in: Thirase, G.; Weiss, E. J. Organomet. Chem. 1974, 81, C1.
2. See for example: Houben-Weyl. Methoden der Organischen Chemie; Thieme: Stuttgart, Germany, 1970; Vol. XIII 1. The synthesis of halide-free NaPh was first described in: Thirase, G.; Weiss, E. J. Organomet. Chem. 1974, 81, C1.
3. Schümann, U.; Behrens, U.; Weiss, E. Angew. Chem., Int. Ed. Engl. 1989, 28, 476.
4. Schümann, U.; Weiss, E. Angew. Chem., Int. Ed. Engl. 1988, 27, 584.
5. den Besten, R.; Brandsma, L.; Spek, A. L.; Kanters, J. A.; Veldman, N. J. Organomet. Chem. 1995, 498, C6.
6. Ruhlandt-Senge, K.; Ellison, J.; Wehmschulte, R. J.; Pauer, F.; Power, P. P. J. Am. Chem. Soc. 1993, 115, 11353.
7. Schiemenz, B.; Power, P. P. Angew. Chem., Int. Ed. Engl. 1996, 35, 2150.
8. Wehmschulte, R. J.; Power, P. P. J. Am. Chem. Soc. 1997, 119, 2847.
9. -1): 1722 vw, 1612 s, 1560 m, 1480 sh, 1245 w, 1169 vw, 1097 vw, 1087 w, 1026 m, 1009 w, 846 vs, 802 s, 781 w, 739 s, 573 w, 545 sh, 492 w, 333 w, 270 w.
10. -1): 1731 w, 1602 ms, 1580 m, 1209 ms, 1156 w, 1085 m, 1062 ms, 1030 m, 1008 m, 973 vw, 950 vw, 884 vw, 851 vs, 794 s, 775 w, 747 sh, 740 m, 722 s, 630 m, 567 w, 541 vw, 301 m, 263 m.
11. 1 = 0.057 for 7665 (I > 2σ(I)) reflections.
12. 1 = 0.045 for 2232 (I > 2σ(I)) reflections;
13. 2 with SHELXL-93 (G. M. Sheldrick, Göttingen, Germany, 1993).
14. (a) Huffman, J. C.; Nugent, W. A.; Kochi, J. K. Inorg. Chem. 1980, 19, 2749.
15. (b) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192.
16. Lochmann, L.; Pospísil, J.; Lím, D. Tetrahedron Lett. 1966, 257.
17. 3).
18. Hitchcock, P. B.; Lappert, M. F.; Leung, W.-P.; Diansheng, L.; Shun, T. J. Chem. Soc., Chem. Commun. 1993, 1386.
19. Al-Juaid, S. S.; Eaborn, C.; Hitchcock, P. B.; Izod, K.; Mallien, M.; Smith, J. D. Angew. Chem., Int. Ed. Engl. 1994, 33, 1268.