Synthesis of gallium chalcogenide cubanes and their use as CVD precursors for Ga2E3 (E = S, Se)

Organometallics

Volumn 15, Issue 22, 1996, Pages 4880-4883

  Schulz, Stephan ^a   Gillan, Edward G ^b   Ross, Jean L ^a   Rogers, Lillian M ^c   Rogers, Robin D ^c   Barron, Andrew R ^b  

^a E11 SSH   (United States)

^b RICE UNIVERSITY   (United States)

^c UNIVERSITY OF ALABAMA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000684923     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960480w     Document Type: Article

References (39)

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3. See for example: (a) Maclnnes, A. N.; Power, M. B.; Barron, A. R. Chem. Mater. 1992, 4, 11. (b) MacInnes, A. N.; Power, M. B.; Barron, A. R. Chem. Mater. 1993, 5, 1344. (c) Cheon, J.; Arnold, J.; Yu, K.-M.; Bourret, E. D. Chem. Mater. 1995, 7, 2274.
4. See for example: (a) Maclnnes, A. N.; Power, M. B.; Barron, A. R. Chem. Mater. 1992, 4, 11. (b) MacInnes, A. N.; Power, M. B.; Barron, A. R. Chem. Mater. 1993, 5, 1344. (c) Cheon, J.; Arnold, J.; Yu, K.-M.; Bourret, E. D. Chem. Mater. 1995, 7, 2274.
5. See for example: (a) Sze, S. M. Semiconductor Devices, Physics and Technology; John Wiley and Sons: Chichester, U.K., 1985. (b) MacInnes, A. N.; Cleaver, W. M.; Barron, A. R.; Power, M. B.; Hepp, A. F. Adv. Mater. Opt. Electron. 1992, 1, 229. (c) Ando, K.; Katsui, A. Thin Sold Films 1981, 76, 141.
6. See for example: (a) Sze, S. M. Semiconductor Devices, Physics and Technology; John Wiley and Sons: Chichester, U.K., 1985. (b) MacInnes, A. N.; Cleaver, W. M.; Barron, A. R.; Power, M. B.; Hepp, A. F. Adv. Mater. Opt. Electron. 1992, 1, 229. (c) Ando, K.; Katsui, A. Thin Sold Films 1981, 76, 141.
7. See for example: (a) Sze, S. M. Semiconductor Devices, Physics and Technology; John Wiley and Sons: Chichester, U.K., 1985. (b) MacInnes, A. N.; Cleaver, W. M.; Barron, A. R.; Power, M. B.; Hepp, A. F. Adv. Mater. Opt. Electron. 1992, 1, 229. (c) Ando, K.; Katsui, A. Thin Sold Films 1981, 76, 141.
8. See for example: (a) Maclnnes, A. N.; Power, M. B.; Barron, A. R.; Jenkins, P. P.; Hepp, A. F. Appl. Phys. Lett. 1993, 62, 711. (b) Maclnnes, A. N.; Power, M. B.; Barron, A. R.; Jenkins, P. P.; Hepp, A. F. Mater. Res. Soc., Symp. Proc. 1993, 282, 111. (c) Tabib-Azar, M.; Kang, S.; Maclnnes, A. N.; Power, M. B.; Jenkins, P. P.; Hepp, A. F.; Barron, A. R. Appl. Phys. Lett. 1993, 63, 625.
9. See for example: (a) Maclnnes, A. N.; Power, M. B.; Barron, A. R.; Jenkins, P. P.; Hepp, A. F. Appl. Phys. Lett. 1993, 62, 711. (b) Maclnnes, A. N.; Power, M. B.; Barron, A. R.; Jenkins, P. P.; Hepp, A. F. Mater. Res. Soc., Symp. Proc. 1993, 282, 111. (c) Tabib-Azar, M.; Kang, S.; Maclnnes, A. N.; Power, M. B.; Jenkins, P. P.; Hepp, A. F.; Barron, A. R. Appl. Phys. Lett. 1993, 63, 625.
10. See for example: (a) Maclnnes, A. N.; Power, M. B.; Barron, A. R.; Jenkins, P. P.; Hepp, A. F. Appl. Phys. Lett. 1993, 62, 711. (b) Maclnnes, A. N.; Power, M. B.; Barron, A. R.; Jenkins, P. P.; Hepp, A. F. Mater. Res. Soc., Symp. Proc. 1993, 282, 111. (c) Tabib-Azar, M.; Kang, S.; Maclnnes, A. N.; Power, M. B.; Jenkins, P. P.; Hepp, A. F.; Barron, A. R. Appl. Phys. Lett. 1993, 63, 625.
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13. For leading references, see for example: (a) Oliver, J. P.; Kumar, R.; Taghiof, M. In Coordination Chemistry of Aluminum; Robinson, G. H., Ed.; VCH: New York, 1993; p 167. (b) Rahbarnoohi, H.; Kumar, R.; Heeg, M. J.; Oliver, J. P. Organometallics 1995, 14, 3869. (c) Haggata, S. W.; Azad Malik, M.; Motevalli, M.; O'Brien, P. Chem. Mater. 1995, 7, 716. (d) Taghiof, M.; Heeg, M. J.; Bailey, M.; Dick, D. G.; Kumar, R.; Hendershot, D. G.; Rahbarnoohi, H.; Oliver, J. P. Organometallics 1995, 14, 2903.
14. For leading references, see for example: (a) Oliver, J. P.; Kumar, R.; Taghiof, M. In Coordination Chemistry of Aluminum; Robinson, G. H., Ed.; VCH: New York, 1993; p 167. (b) Rahbarnoohi, H.; Kumar, R.; Heeg, M. J.; Oliver, J. P. Organometallics 1995, 14, 3869. (c) Haggata, S. W.; Azad Malik, M.; Motevalli, M.; O'Brien, P. Chem. Mater. 1995, 7, 716. (d) Taghiof, M.; Heeg, M. J.; Bailey, M.; Dick, D. G.; Kumar, R.; Hendershot, D. G.; Rahbarnoohi, H.; Oliver, J. P. Organometallics 1995, 14, 2903.
15. For leading references, see for example: (a) Oliver, J. P.; Kumar, R.; Taghiof, M. In Coordination Chemistry of Aluminum; Robinson, G. H., Ed.; VCH: New York, 1993; p 167. (b) Rahbarnoohi, H.; Kumar, R.; Heeg, M. J.; Oliver, J. P. Organometallics 1995, 14, 3869. (c) Haggata, S. W.; Azad Malik, M.; Motevalli, M.; O'Brien, P. Chem. Mater. 1995, 7, 716. (d) Taghiof, M.; Heeg, M. J.; Bailey, M.; Dick, D. G.; Kumar, R.; Hendershot, D. G.; Rahbarnoohi, H.; Oliver, J. P. Organometallics 1995, 14, 2903.
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23. Our initial efforts in this area have involved the photoassisted MOCVD of GaS thin films; see: Pernot P.; Barron, A. R. Chem. Vap. Deposition 1995, 1, 75.
24. n-, show distortion due to crystal packing forces; see: Snyder, B. S.; Holm, R. H. Inorg. Chem. 1988, 27, 2339 and references therein.
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27. 5-coordination or ring-wizzing in solution at room temperature.
28. See: Cleaver, W. M.; Barron, A. R.; McGufey, A. R.; Bott, S. G. Polyhedron 1994, 13, 2831 and references therein.
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30. 3 are thermodynamically stable compositions for these systems; see: Binary Alloy Phase Diagrams; Massalski, T. B., Ed.; ASM Intl.: Materials Park, OH, 1990; Vol. 2, p 1849.
31. 4 is only observed above 450 °C; see ref 12 and 3b.
32. 3).
33. Warren, B. E. X-Ray Diffraction; Dover Publications: New York, 1990; p 253.
34. Detty, M. R.; Seidler, M. D. J. Org. Chem. 1982, 47, 1354.
35. Koch, H.-J. Ph.D. Thesis, University of Göttingen, 1992.
36. Schulz, S. Diplom, University of Göttingen, 1991.
37. Purification of compounds 1-3 by recrystallization is preferable to sublimation, since some decomposition was observed even under vacuum sublimation.
38. SHELXTL V. 5.0: Siemens Industrial Automation, Analytical Instrumentation Business Unit, Madison, WI, 1996.
39. Landry, C. C.; Cheatham, L. K.; Maclnnes, A. N.; Barron, A. R. Adv. Mater. Opt. Electron. 1992, 1, 3.