Reaction of phosphites with the electrophilic allenyl complex[Fe2(CO) 6(μ-PPh2){μ-η1:η2-(H)Cα =Cβ=CγH2}]: Stepwise transformation of a μ-η 1:η2-allenyl into a μ-η1:η2-acetylide vs phosphite activation

Organometallics

Volumn 16, Issue 20, 1997, Pages 4251-4253

  Doherty, Simon ^a   Elsegood, Mark R J ^a   Clegg, William ^a   Ward, Mark F ^a   Waugh, Mark ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000681375     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9704760     Document Type: Article

References (27)

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17. 2: C, 48.39; H, 4.21. Found: C, 48.33; H, 4.04.
18. 2: C, 46.76; H, 3.77. Found: C, 47.08; H, 3.39.
19. 2 for all data, and 364 refined parameters.
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22. int = 0.0316). Corrections, structure solution, and refinement were as for 2a: transmission 0.744-0.905, no disorder, wR2 = 0.0947, conventional R = 0.0362 (3549 reflections), S = 1.056, and 331 refined parameters. Programs used were standard control software, SHELXTL (Siemens Analytical X-ray Instrumentation Inc., Madison, Wi., version 5, 1994) and local programs.
23. (a) Yu, Y.; Jablonski, C.; Bridson, J. Organometallics 1997, 16, 1270.
24. (b) Nakazawa, H.; Ueda, Y.; Nakamura, K.; Miyoshi, K. Organometallics 1997, 16, 1562.
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27. Doherty, S.; Elsegood, M. R. J.; Clegg, W.; Waugh, M. Manuscript in preparation.