Viscosity, fragility, and configurational entropy of melts along the join SiO2-NaAlSiO4

American Mineralogist

Volumn 82, Issue 9-10, 1997, Pages 979-990

  Toplis, Michael J ^a,b   Dingwell, Donald B ^a   Hess, Kai Uwe ^a   Lenci, Tommaso ^a  

^a UNIVERSITÄT BAYREUTH   (Germany)

^b CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ALUMINUM METALLOGRAPHY; ENTROPY; FELDSPAR; GLASS; GLASS TRANSITION; LOW TEMPERATURE EFFECTS; MIXING; PHASE EQUILIBRIA; SILICA; SILICON; SODIUM ALUMINATE; SPECIFIC HEAT; TEMPERATURE DISTRIBUTION; TEMPERATURE MEASUREMENT; TOPOLOGY; VISCOSITY;

ADAM-GIBBS THEORY; CONCENTRIC CYLINDERS; CONFIGURATIONAL ENTROPY; HEAT-CAPACITY DATA; HIGH TEMPERATURE; LINEAR FUNCTIONS; LOW-TEMPERATURE MEASUREMENTS; TEMPERATURE DEPENDENCE;

SODIUM COMPOUNDS;

EID: 0000675179     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-1997-9-1014     Document Type: Article

References (50)

1. Adam, G. and Gibbs, J.H. (1965) On the temperature dependence of cooperative relaxation properties in glass-forming liquids. Journal of Chemical Physics, 43, 139-146.
2. Angell, C.A. (1985) Strong and fragile liquids. In K.L. Ngai and G.B. Wright, Eds., Relaxations in complex systems, p. 3-11. U.S. Department of Commerce National Technical Information Service, Springfield, Virginia.
3. Bansal, N.P. and Doremus, R.H. (1986) Handbook of glass properties. 680 p. Academic Press.
4. Böhmer, R. and Angell, C.A. (1992) Correlations of the nonexponentiality and state dependence of mechanical relaxations with bond connectivity in Ge-As-Se supercooled liquids. Physical Review B, 45, 10091-10094.
5. Bottinga, Y. and Richet, P. (1996) Silicate melt structural relaxation: rheology, kinetics, and Adam-Gibbs theory. Chemical Geology, 128, 129-141.
6. Bottinga, Y. and Weill, D.F. (1972) The viscosity of magnetic liquids: a model for calculation. American Journal of Science, 272, 438-475.
7. Bottinga, Y., Richet, P., and Sipp, A. (1995) Viscosity regimes of homogenous silicate melts. American Mineralogist, 80, 305-318.
8. 29Si NMR results. Geochimica et Cosmochimica Acta, 52, 2695-2669.
9. Cohen, M.H. and Grest, G.S. (1979) Liquid-glass transition, a free volume approach. Physical Review B, 20, 1077-1098.
10. Cranmer, D. and Uhlmann, D.R. (1981) Viscosity of liquid albite, a network material. Journal of Non-Crystalline Solids, 45, 283-288.
11. Dingwell, D.B. (1989) Shear viscosities of ferrosilicate liquids. American Mineralogist, 74, 1038-1044.
12. 2. Geochimica et Cosmochimica Acta, 51 195-205.
13. Flood, H. and Knapp, W.J. (1968) Structural characteristics of liquid mixtures of feldspar and silica. Journal of the American Ceramic Society, 51, 259-263.
14. Götze, W. (1991) Aspects of structural glass transition. In J.P. Hansen, D. Levesque, and J. Zin-Justin, Eds., Liquids, freezing, and glass transition. Volume 1, p. 292-503. Elsevier, Amsterdam.
15. Hess, K-U. (1996) Zur Temperaturabhängigkeit der Viscosität von haplogranitischen Schmelzen, Ph.D thesis, Universität Bayreuth, Germany.
16. Hess, K-U., Dingwell, D.B., and Webb, S.L. (1995) The influence of excess alkalis on the viscosity of a haplogranitic melt. American Mineralogist, 80, 297-304.
17. Hummel, W. and Arndt, J. (1985) Variation of viscosity with temperature and composition in the plagioclase system. Contributions to Mineralogy and Petrology, 90, 83-92.
18. Hunold, V.K. and Brückner, R. (1980) Physikalische Eigenschaften und struktereller Feinbau von Natrium-Aluminosilicatgläsern und-schmelzen. Glastechische Berichte, 6, 149-161.
19. Lacy, E.D. (1963) Aluminum in glasses and melts. Physics and Chemistry of Glasses, 4, 234-238.
20. Loewenstein, W. (1954) The distribution of aluminium in the tetrahedra of silicates and aluminates. American Mineralogist, 39, 92-96.
21. 2 glasses. Journal of Physical Chemistry, 95, 6822-6827.
22. Matson, D.W., Sharma, S.K., and Philpotts, J.A. (1986) Raman spectra of some tectosilicates and glasses along the orthoclase-anorthite and nepheline-anorthite joins. American Mineralogist, 71, 694-704.
23. Mazurin, O.V., Streltsina, M.V., and Shvaiko-shvaikovskaya, T.P. (1987) Handbook of glass data. Part C: Ternary silicate glasses. Physical Sciences Data 15, p. 1110. Elsevier, Amsterdam.
24. _ (1993) Handbook of glass data. Part E: Supplement to parts A-D. Physical Sciences Data 15, p. 875, Elsevier.
25. McMillan, P., Piriou, B., and Navrotsky, A. (1982) A Raman spectroscopic study of glasses along the joins silica-calcium aluminate, silica-sodium aluminate, and silica-potassium aluminate. Geochimica et Cosmochimica Acta, 46, 2021-2037.
26. 29Si NMR study of silicate and aluminosilicate glasses: the effect of network modifying cations. American Mineralogist, 70, 332-343.
27. N'Dala, I., Cambier, F., Anseau, M.R., and Urbain, G. (1984) Viscosity of liquid feldspars Part 1: Viscosity measurements. British Ceramic Transactions and Journal, 83, 105-107.
28. Navrotsky, A., Peraudeau, G., McMillan, P., and Coutures, J-P. (1982) A thermochemical study of glasses and crystals along the joins silicacalcium aluminate and silica-sodium aluminate. Geochimica et Cosmochimica Acta, 46, 2039-2047.
29. Neuville, D.R. (1992) Etude des propriétés thermodynamiques et rhéologiques des silicates fondus. Ph.D. thesis, Université de Paris 7 - spécialité géochimie fondamentale.
30. 2. Geochimica et Cosmochimica Acta, 60, 1727-1737.
31. Neuville, D.R. and Richet, P. (1991) Viscosity and mixing in molten (Ca, Mg) pyroxenes and garnets. Geochimica et Cosmochimica Acta, 55, 1011-1019.
32. 29Si NMR spectroscopy of framework-aluminosilicate glasses. Geochimica et Cosmochimica Acta, 51, 2199-2210.
33. Plazek, D.J. and Ngai, K.L. (1991) Correlation of polymer segmental chain dynamics with temperature dependent time-scale shifts. Macromolecules, 24, 1222-1224.
34. Richet, P. (1984) Viscosity and configurational entropy of silicate melts. Geochimaica et Cosmochimica Acta, 48, 471-483.
35. 8. Geochimica et Cosmochimica Acta, 48, 433-470.
36. _ (1985) Heat capacity of aluminum-free liquid silicates. Geochimica et Cosmochimica Acta, 49, 471-486.
37. _ (1995): Rheology and configurational entropy of silicate melts. In Mineralogical Society of America Reviews in Mineralogy 32, 67-93.
38. Richet, P. and Neuville, D.R. (1992) Thermodynamics of silicate melts: configurational properties. In S. Saxena, Ed., Thermodynamic Data. Systematics and Estimation, Advances in Physical Geochemistry, p. 132-160. Springer-Verlag, Berlin.
39. 4 glass, liquid, and polymorphs. Physics and Chemistry of Minerals, 17, 385-394.
40. 2 at 1500°C. Journal of Chemical Physics, 44, 2857-2865.
41. Scamehorn, C. and Angell, C.A. (1991) Viscosity-temperature relations and structure in fully polymerised aluminosilicate melts from ion dynamics simulations. Geochimica et Cosmochimica Acta, 55, 721-730.
42. Shaw, H.R. (1972) Viscosities of magmatic silicate liquids: an empirical method of prediction. American Journal of Science, 272, 870-893.
43. 4. American Mineralogist, 67, 696-717.
44. 2: Implications for structure and dynamics. American Mineralogist, 78, 710-728.
45. 2: Methodology and melt structures. American Mineralogist, 80, 417-431.
46. Tauber, P. and Arndt, J. (1987) The relationship between viscosity and temperature in the system anorthite-diopside. Chemical Geology, 62, 71-81.
47. 4 join. Geochimica et Cosmochimica Acta, 43, 1467-1475.
48. Taylor, T.D. and Rindone, G.E. (1970) Properties of aluminosilicate glasses. V. Low temperature viscosities. Journal of the American Ceramic Society, 53, 692-695.
49. 5 on the viscosity of melts of differing alkali/aluminium ratio: Implications for me structural role of phosphorus in silicate melts. Geochimica et Cosmochimica Acta, 60, 4107-4121.
50. 2 liquids: The role of triclusters in tectosilicate melts. Geochimica et Cosmochimica Acta, 61, 2605-2612.