Three-dimensional metal piperazinyldiphosphonate phases with ellipsoidal cavities defined by 44-membered rings: Crystal structures of [M{O3PCH2NH(C2H4) 2NHCH2PO3}] · H2O, M = Mn and Co

Journal of Solid State Chemistry

Volumn 123, Issue 2, 1996, Pages 408-412

  LaDuca, Robert ^a   Rose, David ^a   DeBord, Jeffrey R D ^a,b   Haushalter, Robert C ^b   O'Connor, Charles J ^c   Zubieta, Jon ^a  

^a SYRACUSE UNIVERSITY   (United States)

^b NEC LABORATORIES AMERICA   (United States)

^c UNIVERSITY OF NEW ORLEANS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000659287     PISSN: 00224596     EISSN: None     Source Type: Journal    
DOI: 10.1006/jssc.1996.0196     Document Type: Article

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38. -1): 1, 3398(s, br), 2950 (w), 1676(w), 1452(m), 1263(s), 1074(s), 995(s), 962(m), 778(w). 2, 3467(s, br), 3023 (w), 2990(w), 1663(m), 1522(m), 1437(m), 1069(s), 993(s), 960(m), 780(m), 567(m), 545(m).
39. 0) converged at R = 0.083. In both cases, data was collected on a Rigaku AFC-5S diffractometer using graphite crystal-monochromated MoKα radiation (λ = 0.71073Å) with 2θ-ω scans. An empirical absorption correction was applied. The structure was determined by direct methods using the SHLEXTL PLUS solution and refinement programs. All non-hydrogen atoms were defined anisotropically; hydrogen atoms were located in idealized positions.
40. 2O, respectively, over the 2-300 K temperature range using a Quantum Design MPMS-5S SQUID susceptometer. Measurement and calibration techniques have been reported elsewhere (34). The temperature dependent magnetic data were measured at a magnetic field of 1000 G.
41. C. J. O'Connor, Prog. Inorg. Chem. 29, 203 (1982).
42. 12J/κT.
43. B)χ′, where χ′ is the magnetic susceptibility of the material in the absence of the exchange field and χ is the molecular exchange field influenced magnetic susceptibility that is actually measured. The exchange field coupling parameter is zJ′, where z is the number of exchange coupled neighbors.