Syntheses and structure of new dinuclear palladium(II) complexes with 1,1,2,2-tetraacetylethanate and β-diketonate

Chemistry Letters

Volumn , Issue 8, 1996, Pages 663-664

  Kobayashi, Yumiko ^a   Nagao, Noriharu ^a   Okeya, Seichi ^b   Fukuda, Yutaka ^a  

^a OCHANOMIZU UNIVERSITY   (Japan)

^b WAKAYAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000647546     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.663     Document Type: Article

References (11)

1. Y. Fukuda and K. Mafune, Chem. Lett, 1988, 697.
2. H. Kambayashi, J. Yuzurihara, Y. Masuda, H. Nakagawa, W. Linert, and Y Fukuda, Z. Naturtorsch., 506, 536(1995).
3. W. Linert, B. Pouresmaeil, V. Gutmann, K. Mafune, Y. Fukuda, and K. Sone, Monatsh. Chem., 121, 765(1990).
4. S. Okeya, S. Ooi, K. Matsumoto, Y. Nakamura, and S. Kawaguchi, Bull. Chem. Soc. Jpn., 54, 1085(1981).
5. A. R. Siedle and L. H. Pignolet, Inorg. Chem., 21, 3090(1982).
6. 3C=O).
7. +. Although the complex 2b is by product in this synthesis, the complex is potential precursor Tor synthesis of any multinuclear complex or any dinuclear complex having different metal ion.
8. -).
9. 3, R = 0.047 (Rw =0.045) on 5240 reflection (I> 3σ(I)). 10 The structure data of one more Pd(3)-Pd(4) dinuclear unit : Pd(3)-O(9), 2.001(6); Pd(3)-O(10), 2.011(6); Pd(S)-O(11), 1.943(6); Pd(3)-O(12), 1.978(6); Pd(4)-O(13), 1.991(7); Pd(4)-O(14), 1.997(7); Pd(4)-O(15), 1.938(6); Pd(4)-O(16), 1.962(6); O(9)-Pd(3)-O(10), 93.0(3); O(11)-Pd(3)-O(12), 93.3(2); O(13)-Pd(4)-O(14), 94.1(3); O(15)-Pd(4)-O(16), 93.6(2).
10. A. R. Siedle, R.A. Newmark, A. A. Kruger, and L. H. Pignolet, Inorg. Chem., 20, 3399(1981).
11. 3, R =0.033 (Rw =0.025) on 1760 reflection (I> 3σ(I)).