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Volumn 26, Issue 42, 1985, Pages 5139-5142

Stereoselective reduction of α-alkoxy acetylenic ketones with zinc borohydride and K-selectride.

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Indexed keywords


EID: 0000633376     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)98885-3     Document Type: Article
Times cited : (60)

References (7)
  • 5
    • 0000546839 scopus 로고
    • Chelation-controlled nucleophilic additions. 2. A highly effective system for asymmetric induction in the reaction of organometallics with β-alkoxyaldehydes.
    • Based on Still's results, that threo-selection was observed in the nucleophilic addition of Grignard reagent to α-alkoxy aldehyde, we first examined the reaction of Grignard reagent i with the α-alkoxy aldehyde ii. However all attempts, changing the reaction temperature (−30°C−110°C), the protecting groups and additive metals, gave roughly 1:1 mixture of products.
    • (1980) Tetrahedron Letters , vol.21 , pp. 1035
    • Still1    Schneider2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.