2,6-Dimethoxyphenylphosphetane sulfide - synthesis, structure and exploratory photochemistry

Journal of Organometallic Chemistry

Volumn 585, Issue 1, 1999, Pages 167-173

  Qian, Hu ^a   Gaspar, Peter P ^a   Rath, Nigam P ^b  

^a WASHINGTON UNIVERSITY   (United States)

^b UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

Methylene(thioxo)phosphorane; Phosphetane sulfide; Phosphinidene sulfide

Indexed keywords

EID: 0000631203     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(99)00210-7     Document Type: Article

References (36)

1. P.P. Gaspar, R. West, in: Z. Rappoport, Y. Apeloig (Eds.), The Chemistry of Organosilicon Compounds, Wiley, Chichester, 1998, Ch. 43.
2. Gusel'nikov L.E., Nametkin N.S. Chem. Rev. 79:1979;529.
3. M.P. Egorov, P.P. Gaspar, in: R.B. King (Ed.), The Encyclopedia of Inorganic Chemistry, vol. 3, Wiley, Chichester, 1994, pp. 1292-1319.
4. Namavari M., Conlin R.T. Organometallics. 11:1992;3307.
5. X. Li, D. Lei, M.Y. Chiang, P.P. Gaspar, J. Am. Chem. Soc. 114 (1992) 8526; P, S, Si, and Rel. Elem. 76 (1993) 71.
6. X. Li, D. Lei, M.Y. Chiang, P.P. Gaspar, J. Am. Chem. Soc. 114 (1992) 8526; P, S, Si, and Rel. Elem. 76 (1993) 71.
7. S. Haber, P. LeFloch, F. Mathey, J. Chem. Soc. Chem. Commun. (1992) 1799; P, S, Si, and Rel. Elem. 75 (1993) 225.
8. S. Haber, P. LeFloch, F. Mathey, J. Chem. Soc. Chem. Commun. (1992) 1799; P, S, Si, and Rel. Elem. 75 (1993) 225.
9. Li X., Weissman S.I., Lin T.-S., Gaspar P.P., Cowley A.H., Smirnov A.I. J. Am. Chem. Soc. 116:1994;7899.
10. Berger D.J., Gaspar P.P., LeFloch P., Mathey F., Grev R.S. Organometallics. 15:1996;4904.
11. P.P. Gaspar, A.M. Beatty, X. Li, H. Qian, N.P. Rath, J.C. Watt, P, S, Si, and Rel. Elem., in press.
12. W.W. Schoeller, E. Niecke, J. Chem. Soc. Chem. Commun. (1982) 569.
13. P.P. Gaspar, X. Li, J. Silverman, T. Haile, D.H. Pae, M. Xiao in: B. Marciniec, J. Chojnowski (Eds.), Progress in Organosilicon Chemistry, Gordon and Breach, 1995, pp. 247-262.
14. T. Osahikawa, M. Yamashishita, Synthesis (1985) 290.
15. Li X., Robinson K.D., Gaspar P.P. J. Org. Chem. 61:1996;7702.
16. Marinetti A., Kruger V., Buzin F.-X. Tetrahedron Lett. 38:1997;2947.
17. The two conformers shown in Figures 1 and 2 were not separated. They occur together in the unit cell.
18. The two molecules in the unit cell differ in geometry as indicated in Table 1.
19. Marinetti A., Ricard L. Tetrahedron. 49:1993;10291.
20. Bachrach S.M. J. Phys. Chem. 93:1989;7780.
21. A. Marinetti, F. Mathey, J. Chem. Soc. Chem. Commun. (1990) 153.
22. P.P. Gaspar, H. Qian, A.M. Beatty, D.A. d'Avignon, J.L.-F. Kao, J.C. Watt, N.P. Rath, Tetrahedron, in press.
23. 3) 22.3 and 4.8, respectively: S. Kobayashi, M. Suzuki, T. Saegusa, Bull. Chem. Soc. Jpn. 58 (1985) 2153.
24. 2P(S)OMe.
25. 2P(S)OMe.
26. Yoshifuji M., Tagawa J., Inamoto N. Tetrahedron Lett. 20:1979;2415.
27. 3) 92.5.
28. 2) 89.6.
29. H.G. Cook, J.D. Ilett, B.C. Saunders, G.J. Stacey, H.G. Watson, I.G.E. Wilding, S.J. Woodcock, J. Chem. Soc. (1949) 2922.
30. Fluck E., Van Wazer J.R. Anorg. Allg. Chem. 307:1961;113.
31. Corey E.J., Mitra R.B. J. Am. Chem. Soc. 84:1962;2938.
32. Brucker Analytical X-Ray Division, Madison, WI, 1998.
33. Blessing R.H. Acta Crystallogr. A51:1995;33.
34. G.M. Sheldrick, Bruker Analytical X-Ray Division, Madison, WI, 1998.
35. M.L. Dhar, E.D. Hughes, C.K. Ingold, J. Chem. Soc. (1948) 2058.
36. Brown M.S., Mayne C.L., Grant D.M., Chou T.C., Allred E.L. J. Phys. Chem. 88:1984;2708.