메뉴 건너뛰기




Volumn 95, Issue 7, 1995, Pages 2485-2506

Asymmetric Hydroformylation

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0000613575     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/cr00039a008     Document Type: Article
Times cited : (448)

References (112)
  • 1
    • 0003720729 scopus 로고
    • Springer Verlag: New York, 1970; New Syntheses with Carbon Monoxide; Springer Verlag: New York
    • Falbe, J. Carbon monoxide in Organic Synthesis; Springer Verlag: New York, 1970; New Syntheses with Carbon Monoxide; Springer Verlag: New York, 1980.
    • (1980) Carbon monoxide in Organic Synthesis
    • Falbe, J.1
  • 4
    • 85022571996 scopus 로고
    • see: Consiglio, G. In Catalysis in Asymmetric Synthesis; Ojima, I., Ed.; VCH Publishers Inc.: New York
    • For a general recent review article on asymmetric hydroformylation, see: Consiglio, G. In Catalysis in Asymmetric Synthesis; Ojima, I., Ed.; VCH Publishers Inc.: New York, 1993; pp 273-302.
    • (1993) For a general recent review article on asymmetric hydroformylation , pp. 273-302
  • 5
    • 85022568262 scopus 로고
    • e.g. 3-methyl-l-pentene, in which an enantiomer-discriminating process may occur, presents a further possibility of obtaining optically active aldehydes. This type of asymmetric hydroformylation has been achieved in the first stage of research and was reviewed in. See ref 12
    • The hydroformylation of racemic olefins, e.g. 3-methyl-l-pentene, in which an enantiomer-discriminating process may occur, presents a further possibility of obtaining optically active aldehydes. This type of asymmetric hydroformylation has been achieved in the first stage of research and was reviewed in 1982. See ref 12.
    • (1982) The hydroformylation of racemic olefins
  • 11
    • 85022498000 scopus 로고
    • Ph. D. Dissertation,, 1974; Chem. Abstr.
    • Hsu, C. Y. Ph. D. Dissertation, University of Cincinnatti, 1974; Chem. Abstr. 1975, 82, 154899.
    • (1975) University of Cincinnatti , vol.82 , pp. 154899
    • Hsu, C.Y.1
  • 13
    • 85022571913 scopus 로고
    • It is noteworthy that in the early stage of research (up to), because of an erroneous value for the specific rotation value of pure hydratropaldehyde. Some of these results are reported in this paper, but the ee's have been revalued (lowered) according to the exact specific rotation determined by Pittman, 27 i.e. [a]21n = 315.8° (ca. 1.5 g in 100 mL of benzene) or [a]2ID = 238° (neat) for pure 2-phenylpropanal.
    • It is noteworthy that in the early stage of research (up to 1983), many optical yields for the hydroformylation product of styrene were overestimated, because of an erroneous value for the specific rotation value of pure hydratropaldehyde. Some of these results are reported in this paper, but the ee's have been revalued (lowered) according to the exact specific rotation determined by Pittman, 27 i.e. [a]21n = 315.8° (ca. 1.5 g in 100 mL of benzene) or [a]2ID = 238° (neat) for pure 2-phenylpropanal.
    • (1983) many optical yields for the hydroformylation product of styrene were overestimated
  • 43
    • 85022454540 scopus 로고    scopus 로고
    • Actually, the corresponding experiments of BCO type systems were carried out under elevated pressure (CO/H2 = 70/140 atm), and this could also account, at least in part
    • Actually, the corresponding experiments of BCO type systems were carried out under elevated pressure (CO/H2 = 70/140 atm), and this could also account, at least in part, for the high catalytic rates as shown in section II.B.3 devoted to the influence of pressure.
    • for the high catalytic rates as shown in section II.B.3 devoted to the influence of pressure.
  • 91
    • 0004034472 scopus 로고
    • PCT Int. Appl. WO 93 03839, 1993; 119, 159872h.
    • Babin, J. E.; Whiteker, G. T. PCT Int. Appl. WO 93 03839, 1993; Chem. Abstr. 1993, 119, 159872h.
    • (1993) Chem. Abstr.
    • Babin, J.E.1    Whiteker, G.T.2
  • 98
    • 85022499810 scopus 로고    scopus 로고
    • the branched hydroformylation product of methyl acrylate is in equilibrium with its enol form (both tautomers observed in NMR spectroscopy), that quickly results in a racemic mixture. The ee values in this article for substrates other than methyl acrylate are correctly reported.
    • Personnal communication from Dr. Felice Faraone. In fact, the branched hydroformylation product of methyl acrylate is in equilibrium with its enol form (both tautomers observed in NMR spectroscopy), that quickly results in a racemic mixture. The ee values in this article for substrates other than methyl acrylate are correctly reported.
    • Personnal communication from Dr. Felice Faraone. In fact
  • 108
    • 85022515908 scopus 로고
    • Shokubai 1994, 36, 259 (in Japanese);, 121, 300137x.
    • Takaya, H.; Nozaki, K. Shokubai 1994, 36, 259 (in Japanese); Chem. Abst. 1994, 121, 300137x.
    • (1994) Chem. Abst.
    • Takaya, H.1    Nozaki, K.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.