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Volumn 430, Issue 3, 1992, Pages

Sterically induced opening of a closo carbametallaborane: synthesis and characterisation of 1,2-Ph2-3-(η-C5Me5)-3,1,2-pseudocloso-RhC2B9H9

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Indexed keywords


EID: 0000607140     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(92)83273-K     Document Type: Article
Times cited : (41)

References (22)
  • 6
    • 84917942011 scopus 로고    scopus 로고
    • Z.G. Lewis and A.J. Welch, Acta Crystallogr., in preparation.
  • 10
    • 84917942010 scopus 로고    scopus 로고
    • The H(12) ţdot; H(22) contact distances are only 1.71 Å in molecule A and 1.85 Å in molecule B.
  • 11
    • 84917942009 scopus 로고    scopus 로고
    • The orientation of the phenyl rings may be conveniently described by θ, the difference between 90° and the average CC(1)C(2)C torsion angle. In II θ is 83° for both molecule A and molecule B.
  • 12
    • 84917942008 scopus 로고    scopus 로고
    • θ = 6° and C(1)C(2) = 1.727 A (average of two crystallographically independent molecules).
  • 14
    • 84917942007 scopus 로고    scopus 로고
    • This is particularly true in II; our adoption of the term pseudocloso and retention of an icosahedral numbering scheme reflect this fact.
  • 18
    • 84917942006 scopus 로고    scopus 로고
    • G.M. Sheldrick, University of Cambridge, 1976.
  • 21
    • 84917942005 scopus 로고    scopus 로고
    • R.O. Gould, P. Taylor, University of Edinburgh, 1986.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.