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Tetrahedron Letters

Volumn 29, Issue 16, 1988, Pages 1993-1995

Lithiated dihydropyrans as ketone enolate equivalents: A model study for the herbicidins

(5) Cox, Paul a F Mahon, Mary b C Molloy, Kieran c Lister, Simon c Gallagher, Timothy c

a UNIVERSITY OF BATH (United Kingdom)

b WELLCOME RESEARCH LABORATORIES (United Kingdom)

c NONE

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000604754 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(00)82099-7 Document Type: Article

Times cited : (21)

References (26)

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- Enolate von Kohlenhydraten, 4. Axiale α-C-Alkylierung von α-Amino-α-desoxy-Kohlenhydratulosen
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16
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- Stereospecific generation of ?- and ?-glycosyl-lithium reagents from glycosyl-stannanes: a stereocontrolled route to ?- and ?-C-glycosides
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17
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18
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20
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- Synthesis and Reactions of Lithiated p-Dioxene
- 3), is formed as the minor component by silylation of the enolate derived from 2H-dihydropyran-3(4H)one. For anions related to (6) see (a) lithiation of 1,4-dioxene
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23
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- w = 6.75.The ORTEP diagram of cis-(5) is shown in Figure 1.

24
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- eq), [[Truncated]]

25
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- C-H = 5.5 Hz). Although (12a) and (12b) have been separated we have been unable to assign the relative configurations of these ketals. In addition, (12a) and (12b) undergo facile acid-catalysed interconversion.

26
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