95Mo NMR studies on cationic phosphenium complexes of molybdenum

Organometallics

Volumn 15, Issue 10, 1996, Pages 2517-2522

  Nakazawa, Hiroshi ^a   Yamaguchi, Yoshitaka ^a   Miyoshi, Katsuhiko ^b   Nagasawa, Akira ^c  

^a INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^b HIROSHIMA UNIVERSITY   (Japan)

^c SAITAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000599978     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950807d     Document Type: Article

References (48)

1. +.
2. For reviews see: (a) Cowley, A. H.; Kemp, R. A. Chem. Rev. 1985, 85, 367. (b) Sanchez, M.; Mazieres, M. R.; Lamande, L.; Wolf, R. In Multiple Bonds and Low Coordination in Phosphorus Chemistry; Regitz, M., Scherer, O. J., Eds.; Thieme: New York, 1990; Chapter D1.
3. For reviews see: (a) Cowley, A. H.; Kemp, R. A. Chem. Rev. 1985, 85, 367. (b) Sanchez, M.; Mazieres, M. R.; Lamande, L.; Wolf, R. In Multiple Bonds and Low Coordination in Phosphorus Chemistry; Regitz, M., Scherer, O. J., Eds.; Thieme: New York, 1990; Chapter D1.
4. (a) Montemayor, R. G.; Sauer, D. T.; Fleming, S.; Bennett, D. W.; Thomas, M. G.; Parry, R. W. J. Am. Chem. Soc. 1978, 100, 2231.
5. (b) Bennett, D. W.; Parry, R. W. J. Am. Chem. Soc. 1979, 101, 755.
6. (a) Day, V. W.; Tavanaiepour, I.; Abdel-Meguid, S. S.; Kirner, J. F.; Goh, L.-Y.; Muetterties, E. L. Inorg. Chem. 1982, 21, 657.
7. (b) Choi, H. W.; Gavin, R. M.; Muetterties, E. L. J. Chem. Soc., Chem. Commun. 1979, 1085.
8. (c) Muetterties, E. L.; Kirner, J. F.; Evans, W. J.; Watson, P. L.; Abdel-Meguid, S. S.; Tavanaiepour, I.; Day, V. W. Proc. Natl. Acad. Sci. USA 1978, 75, 1056.
9. (a) Cowley, A. H.; Kemp, R. A.; Ebsworth, E. A. V.; Rankin, D. W. H.; Walkinshaw, M. D. J. Organomet. Chem. 1984, 265, C19.
10. (b) Cowley, A. H.; Kemp, R. A.; Wilburn, J. C. Inorg. Chem. 1981, 20, 4289.
11. (a) Nakazawa, H.; Ohta, M.; Yoneda, H. Inorg. Chem. 1988, 27, 973.
12. (b) Nakazawa, H.; Ohta, M.; Miyoshi, K.; Yoneda, H. Organometallics 1989, 8, 638.
13. (c) Nakazawa, H.; Yamaguchi, Y.; Miyoshi, K. J. Organomet. Chem. 1994, 465, 193.
14. (d) Nakazawa, H.; Yamaguchi, Y.; Mizuta, T.; Miyoshi, K. Organometallics 1995, 14, 4173.
15. (e) Nakazawa, H.; Yamaguchi, Y.; Mizuta, T.; Ichimura, S.; Miyoshi, K. Organometallics 1995, 14, 4635.
16. (f) Yamaguchi, Y.; Nakazawa, H.; Itoh, T.; Miyoshi, K. Bull. Chem. Soc. Jpn., in press.
17. (g) Nakazawa, H.; Yamaguchi, Y.; Miyoshi, K. Organometallics 1996, 15, 1337.
18. (a) Dechter, J. J. Prog. Inorg. Chem. 1985, 33, 393.
19. (b) Mason, J. Chem. Rev. 1987, 87, 1299.
20. (a) Minelli, M.; Enemark, J. H.; Brownlee, R. T. C.; O'Connor, M. J.; Wedd, A. G. Coord. Chem. Rev. 1985, 68, 169.
21. (b) Grieves, R. A.; Mason, J. Polyhedron 1986, 5, 415.
22. (c) Render, D. Coord. Chem. Rev. 1991, 110, 161.
23. 95Mo NMR data would be independent of the counteranion. In this paper, a cationic phosphenium complex is described without its counteranion.
24. Christensen, K. A.; Miller, P. E.; Minelli, M.; Rockway, T. W.; Enemark, J. H. Inorg. Chim. Acta 1981, 56, L27.
25. Andrews, G. T.; Colquhoun, I. J.; McFarlane, W.; Grim, S. O. J. Chem. Soc., Dalton Trans. 1982, 2353.
26. (a) Gray, G. M.; Gray, R. J. Organometallics 1983, 2, 1026.
27. (b) Gray, G. M.; Kraihanzel, C. S. Inorg. Chem. 1983, 22, 2959.
28. D-Mtunzi, S.; Hughes, M.; Leigh, G. J.; Ali, H. M.; Richards, R. L.; Mason, J. J. Organomet. Chem. 1983, 246, C1.
29. Bailey, J. T.; Clark, R. J.; Levy, G. C. Inorg. Chem. 1982, 21, 2085.
30. (a) Ramsey, N. F. Phys. Rev. 1950, 77, 567; 1950, 78, 699; 1952, 86, 243.
31. (a) Ramsey, N. F. Phys. Rev. 1950, 77, 567; 1950, 78, 699; 1952, 86, 243.
32. (a) Ramsey, N. F. Phys. Rev. 1950, 77, 567; 1950, 78, 699; 1952, 86, 243.
33. (b) Griffith, J. S.; Orgel, L. E. Trans. Faraday Soc. 1957, 53, 601.
34. (c) Jameson, C. J.; Gutowsky, H. S. J. Chem. Phys. 1964, 40, 1714.
35. (d) Rehder, D. In Multinuclear NMR; Mason, J., Ed.; Plenum Press: New York, 1987; Chapter 19, p 479.
36. (e) Jameson, C. J.; Mason, J. In ref 15d, Chapter 2, p 51.
37. (a) Nakatsuji, H.; Kanda, K.; Endo, K.; Yonezawa, T. J. Am. Chem. Soc. 1984, 106, 4653.
38. (b) Kanda, K.; Nakatsuji, H.; Yonezawa, T. J. Am. Chem. Soc. 1984, 106, 5888.
39. Alyea, E. C.; Topich, J. Inorg. Chim. Acta 1982, 65, L95.
40. Gheller, S. F.; Hambley, T. W.; Brownlee, R. T. C.; O'Connor, M. J.; Snow, M. R.; Wedd, A. G. Aust. J. Chem. 1982, 35, 2183.
41. Minelli, M.; Enemark, J. H.; Wieghardt, K; Hahn, M. Inorg. Chem. 1983, 22, 3952.
42. Alyea, E. C.; Malito, J.; Ernst, S. D.; Kaim, W.; Kohlmann, S. J. Polyhedron 1989, 8, 921.
43. Alyea, E. C.; Gossage, R. A.; Malito, J.; Munir, Z. A. Polyhedron. 1990, 9, 1059.
44. Minelli, M.; Hubbard, J. L.; Enemark, J. H. Inorg. Chem. 1984, 23, 970.
45. Young, C. G.; Kober, E. M.; Enemark, J. H. Polyhedron 1987, 6, 255.
46. Hughes, M.; Mason, J.; Leigh, G. J.; Richards, R. L. J. Organomet. Chem. 1988, 341, 381.
47. Masters, A. F.; Bossard, G. E.; George, T. A.; Brownlee, R. T. C.; O'Connor, M. J.; Wedd, A. G. Inorg. Chem. 1983, 22, 908.
48. 3)]: Alyea, E. C.; Somogyvari, A. Can. J. Chem. 1988, 66, 397.