Is SN2 Substitution with Inversion of Configuration at Vinylic Carbon Feasible?

Journal of the American Chemical Society

Volumn 116, Issue 13, 1994, Pages 5961-5962

  Glukhovtsev, Mikhail N ^a   Pross, Addy ^b   Radom, Leo ^c  

^a SOUTHERN FEDERAL UNIVERSITY   (Russian Federation)

^b BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

^c AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000584171     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00092a054     Document Type: Editorial

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25. -1above 3 (calculated at the G2(+)(MP2) level). The reaction pathways via 2 and 3 are thus discrete. Note that optimizations starting from 2 or 3, seeking a minimum energy structure, lead in both cases to the complex 1. The G2(MP2) procedure is described in the following: Curtiss, L. A.; Raghavachari, K.; Pople, J. A. J. Chem. Phys. 1993, 98, 1293.
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