Homonuclear and heteronuclear oxo-bridged compounds of the transition elements

Polyhedron

Volumn 8, Issue 3, 1989, Pages 219-247

  West, Bruce O ^a  

^a MONASH UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000581548     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(00)80414-3     Document Type: Article

References (339)

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2. The Coordination and Bioinorganic Chemistry of Molybdenum
3. The crystal and molecular structure of bis(biscyclopentadienylchlorotitanium) oxide
4. Studies of Organometallic Compounds XV. The Crystal Structure of Bis(tribenzyl-titanium(IV))-?-oxo
5. The crystal and molecular structure of γ-oxobis[bis(diethyldithiophosphato)oxomolybdenum(V)]–1,2-dichlorobenzene, Mo2O3[S2P(OC2H5)2]4.2C6H4Cl2
6. Crystal and molecular structure of diaquahydrogen(I)�-oxo-[bis(diethyldithiocarbamato)oxomolybdate(IV)][bis(diethyldithiocarbamato)oxomolybdenum(V)] bis{�-oxo-bis[bis(diethyldithiocarbamato)oxomolybdenum(V)]}(1), and �-oxo-bis[bis(diethyldithiocarbamato)oxomolybdenum(V)](2), and the single-crystal electron spin resonance spectrum of (1)
7. Syntheses of NN?-ethylenebis(salicylideneiminate) transition-metal chelates by oxidative decarbonylation
8. Synthesis and characterization of an oxygen-bridged vanadium(III) dimer
9. Crystal and molecular structure of a dinuclear chromium(III) complex with a linear oxygen bridge
10. Dithiocarbamate complexes of rhenium(V) and (III)
11. Preparation, purification, and X-ray crystal structure of a dimeric manganese(IV) porphyrin complex
12. Tetravalent ruthenium porphyrin. II. The molecular and crystal structure of .MU.-oxo-bis((octaethylporphinato)ruthenium(IV) chloride) benzene solvate.
13. The crystal structure of potassium hydroxychlororuthenate, K4Ru2Cl10O.H2O
14. Nouvelle détermination de la structure cristalline du μ-oxo-bis[pentachlororuthénate(IV)] de potassium, K4[Ru2Cl10O] et affinement de la structure de l'hexachlororuthénate de potassium K2[RuCl6]
15. Synthesis and crystal and molecular structure of the oxo-bridged, iron(III) macrocyclic dimer [Fe(C22H22N4)]2O.CH3CN: .mu.-oxo-bis[7,16-dihydro-6,8,16,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato]iron(III)-acetonitrile
16. Crystal and molecular structure of the (.mu.-oxo)bis[aquobis(phenanthroline)iron(III)] complex, a Raman spectroscopic model for the binuclear iron site in hemerythrin and ribonucleotide reductase
17. The composition and magnetic properties of some iron(III) 1,10-phenanthroline and bipyridyl complexes
18. A comparative synthetic and structural study of �-oxo and �-sulphido derivatives of N,N?-ethylenebis(acetylacetoneiminato)iron(III), including the synthesis and structural characterization of the parent compound
19. The crystal and molecular structure of unsolvated μ-oxo-bis[N,N'-ethylenebis(salicylaldiminato)iron(III)]
20. Crystal and molecular structure of �-oxo-bis-[NN?-ethylenebis(salicylideneiminato)iron(III)]?bispyridine
21. Crystal and molecular structure and magnetic anisotropy of �-oxo-bis-[NN?-ethylenebis(salicylideneiminato)iron(III)]?dichloromethane
22. Iron complexes of N-substituted thiosalicylideneimines. Part 1. Synthesis and reactions with oxygen and carbon monoxide
23. The preparation and magnetic properties of some oxy-bridged binuclear iron(III) Schiff-base complexes
24. Crystal and molecular structure and some properties of pyridinium �-oxo-bis[trichioroferrate(III)]?pyridine
25. 528. Application of molecular-orbital theory to some binuclear co-ordination compounds
26. Resonance Raman, infra-red, and electronic spectral studies of the μ-oxo-decachlorodimetallate species, [Ru2OCl10]4-and [Re2OCl10]3-, and related ions
27. Magnetic Properties and Molecular Structure of the mu-Oxo-bis{pentaamminechromium(III)} Ion.
28. Synthesis of niobium(V) porphyrinates. Crystal structures of tri-�-oxo-bis[5,10,15,20-tetraphenylporphyrinatoniobium(V)] and acetato-oxo-(5,10,15,20-tetraphenylporphyrinato)niobium(V)?acetic acid (1/1)
29. [{(C6H15N3)Fe}2(μ-O)(μ-CH3CO2)2]2+ a Dinuclear Iron,(III)Complex with a Metazidohemerythrin-Type Structure
30. Reactivity of the [Fe2(?2-O)(?-acetato)2] Unit in Methemerythrin Model Compounds towards N3? and NCS?
31. Identification and properties of bimetallic intermediates in the hydrolysis of titanium chloro carboxylate species. Crystal structure of Ti2(�-O)(�-O2CPh)2Cl4�2L (L = EtOAc or tetrahydrofuran)
32. Spontaneous self assembly of the {M2(�-O)(�-MeCO2)2}2+ core. Synthesis, structure, and properties of the binuclear vanadium(III) complex
33. Assembly and structural characterization of binuclear �-oxo-di-�-acetato bridged complexes of manganese(III). Analogues of the di-iron(III) centre in hemerythrin
34. Dinuclear Manganese(II,III,IV) Model Complexes for the Active Center of the Metalloprotein Photosystem II: Synthesis, Magnetism, and Crystal Structure of [LMnIII(?-O)(?-CH3CO2)2MnIVL][ClO4]3 (L = N,N?N?-Trimethyl-1,4,7-triazacyclononane)
35. THE METAL CENTERS OF THE PHOTOSYNTHETIC OXYGEN-EVOLVING COMPLEX
36. Synthesis and characterization of the binuclear complex di-�-oxo-bis[N,N?-bis(2-methylpyridyl)ethane-1,2-diamine]dimanganese(III,IV)perchlorate trihydrate,[(bispicen)MnO]2(ClO4)3�3H2O
37. Oxygen Evolution by Water Oxidation Mediated by Heterogeneous Manganese Complexes
38. The crystal structure of a basic chromium acetate compound, [OCr3(CH3COO)6.3H2O]+Cl−.6H2O, having feeble paramagnetism
39. The crystal structure of the basic iron acetate [Fe3(CH3COO)6O.3H2O]+ClO4-(Short communication)
40. Crystal structure and mass spectrum of �3-oxo-hexakis(�-trimethyl-acetato)-trismethanoltri-iron(III) chloride, a trinuclear basic iron(III) carboxylate
41. The reaction between potassium permanganate and formic acid. Structural characterization of the polymeric compound (K2{Mn(H2O)2[Mn3O(HCOO)9]2})n
42. Crystal and molecular structures of trinuclear rhodium(III) complexes: trans-μ3-oxo-tris[bis(acetato)aquarhodium(III)] perchlorate dihydrate and monohydrate
43. Preparation, crystal structure, and magnetic properties of a trinuclear mixed-valence manganese carboxylate
44. Discrete oxidation states and X-ray crystal structure of the trinuclear manganese carboxylate [Mn3(3-ClC5H4N)3O(O2CMe)6]
45. �-Oxo-triruthenium carboxylate complexes
46. Reactions of �3-oxo-triruthenium carboxylates with ?-acid ligands
47. �3-Oxotrimetal acetato-complexes of chromium, manganese, iron, cobalt, rhodium, and iridium
48. Fe3O(OAc)6(Py)3 mediated reduction of aromatic nitro compounds with 2-mercaptoethanol.
49. Oxo-Bridged Polyiron Centers in Biology and Chemistry
50. Modelling the photosynthetic water oxidation centre: synthesis, structure, and magnetic properties of [Mn4O2(OAc)7(biphy)2ClO4]�3H2O (bipy = 2,2?-bipyridine)
51. Support from model studies for the proposed existence of an S?1 oxidation level in the manganese assembly of the photosynthetic water oxidation centre
52. Salicylate-Mediated Assembly of the Diserete Mixed-Valence Nonanuclear Manganese Complex[Mn9O4(O2CPh)8(sal)4(salH)2(py)4](salH2= salicylic acid, py= pyridine)
53. Trinuclear Clusters of the Early Transition Elements
54. Comproportionation synthesis of bi-.mu.3-oxo-capped trimolybdenum(IV) clusters: structural characterization of [Mo3O2(O2CCH3)6(H2O)3](CF3SO3)2
55. Hexa-μ-acetato-di-μ3-oxo-tris[aquatungsten(IV)] trifluoromethylsulfonate
56. Isolation and structure of spatol, a potent inhibitor of cell replication from the brown seaweed Spatoglossum schmittii
57. The structure and reactivity of dioxygen complexes of the transition metals
58. The Crystal Structure of Zinc Oxyacetate, Zn4O(CH3COO)6
59. Binding and Activation of Molecular Oxygen by Copper Complexes
60. Role of a copper complex in an oxygen-atom transfer reaction from dioxygen to triphenylphosphine
61. Synthesis of a novel .MU.-oxo binuclear copper(II) complex ligated by hydrotris(3,5-dimethyl-1-pyrazolyl)borate.
62. An accurate synthetic model of oxyhaemocyanin
63. Preparation, Magnetism, and Crystal Structures of the Tautomers [LCu(?2-OH)2CuL](ClO4)2 (Blue) and [LCu(?2-OH2)(?2-O)CuL](ClO?4)?2 (Green): ?-Aqua-?-oxo vs. Di-?-hydroxo Linkage
64. A penta-indium oxo alkoxide cluster with a central 5-co-ordinate oxygen. Preparation and X-ray crystal structure of (InOPri)5(�2-OPri)4(�3-OPri)4(�5-O)
65. Complexes of molybdenum(VI) and molybdenum(V) with dithiocarbamate, dithiocarbonate, and phosphorothiolothionate
66. Kinetic and mechanistic studies on the disproportionation equilibrium of �-oxo-bis[bis(isopropyl thioxanthato)oxomolybdenum(V)] and on the decomposition reaction of bis(isopropyl thioxanthato)dioxomolybedenum(VI)
67. Oxomolybdenum(IV) complexes
68. The autoxidation of a chromium (II) porphyrin: synthesis and structural characterisation by X-ray crystallography of ????-tetraphenyl-porphinato-oxochromium(IV)
69. The oxidation product of (.beta.-phthalocyaninato)chromium(II)
70. E.s.r. evidence for chromium (V) porphyrinates
71. Organometallic clusters containing oxygen atoms: (?-C5H5)5(O)V6(�3-O)8 and {(?-C5H5)5V6(�-3-O)8}2(�-O), two further derivatives of octahedral (?-C5H5)6V6(�3-O)8
72. Effect of meso substituents on exchange-coupling interactions in .mu.-oxo iron(III) porphyrin dimers
73. Inequivalent clusters and energy transfer in trinuclear chromium(III) acetate
74. Resonance Raman spectra and electronic structure of binuclear .mu.-oxo-bridged decahalo transition metal complexes M2OX104-, M = ruthenium, osmium, tungsten
75. Dissociation of .MU.-oxo-bis[oxobis(8-quinolinolato)vanadium(V)] and .MU.-oxo-bis[oxobis(4-isopropyltropolonato)-vanadium(V)] in chlorobenzene.
76. The Electronic Structure of the Vanadyl Ion
77. Molecular complexes for efficient metathesis of olefins. The oxo-ligand as a catalyst?cocatalyst bridge and the nature of the active species
78. Tungsten(VI) and molybdenumVI oxo-alkyl species. Their role in the metathesis of olefins
79. The crystal and molecular structure of chloro-(NN?-bis-salicylidene-ethylenediamine)iron(III) as a hexaco-ordinate dimer
80. 687. Organosilyloxy-derivatives of metals. Part I. Alkylsilyloxy-derivatives of titanium, zirconium, niobium, and tantalum
81. Bimetallic μ-oxo-alkoxides as catalysts for the insertion polymerization of epoxides
82. Etude des proprietes chimiques et catalytiques d'agregats μ-oxo et μ-alcoxy polynucleaires
83. Cytochrome c oxidase models. A magnetically coupled heme?copper complex
84. A �-oxo mixed-metal complex of copper(II) and an iron(III)-porphyrin as a resting state model for the cytochrome c oxidase active site
85. A dinuclear iron(III) porphyrin?copper(II) complex with a sulphur bridge: a model for the active site of cytochrome c oxidase
86. The formation of heterobinuclear �-oxo Cr?O?Fe porphyrin complexes by the reaction of oxochromium(IV) and iron(II) porphyrins
87. Synthesis of Heterobinuclear Oxo-Bridged Compounds of Chromium, Iron, Manganese and Molybdenum
88. The synthesis of heterobinuclear �-oxo complexes containing Cr?O?Mn, Cr?O?Mo, Mo?O?Fe, and Cr?O?Fe combinations
89. The Synthesis of Oxo-Bridged CrIII-O-VVCompounds
90. Oxygen atom transfer in the oxidation of triphenylphosphine by �-oxo-bis[phthalocyaninatoiron(III)]
91. Proton nuclear magnetic resonance contact shifts of binuclear oxo-bridged iron(III) porphyrins
92. Proton Knight shifts and antiferromagnetic exchange in dimeric oxygenbridged Schiff-base?iron(III) complexes
93. Studies on spin-equilibrium iron(III) complexes. Part 1. Syntheses and magnetic properties of a new family of spin cross-over iron(III) complexes with a unidentate ligand over a wide range of the spectrochemical series and a quinquedentate ligand derived from salicylaldehyde and di(3-aminopropyl)amine. X-Ray crystal structure of [4-azaheptamethylene-1,7-bis(salicylideneiminato)](4-methylpyridine)iron(III) tetraphenylboratet
94. Magnetic and Mössbauer investigations of NN-disubstituted bis(dithiocarbamato)iron(II) complexes
95. Oxygenation reactions of cytochrome oxidase models. Evidence for hematin formation in mononuclear and heterobinuclear complexes
96. N,N-Dialkyldithiocarbamate complexes of niobium(V), vanadium(V), molybdenum(V), molybdenum(VI), and rhenium(v)
97. Investigations of manganese(II) compounds of NN-disubstituted di-thiocarbamates
98. Reactivity of oxomolybdenum(VI), -(V), and -(IV) compounds as controlled by sulfur chelate ligands
99. �ber Ferri-nickel- usw. -acetate und �ber ein sehr basisches kristallisiertes Ferriacetat
100. Exchange interactions in a series of novel heteronuclear basic carboxylate complexes containing two iron(III) ions and a divalent metal ion
101. Heterotrinuclear basic acetates containing chromium(III), iron(III), and a divalent metal: spectroscopic consequences of Metal?Metal interactions
102. Magnetic and spectroscopic properties of some heterotrinuclear basic acetates of chromium(III), iron(III), and divalent metal ions
103. Structure of a Novel ?3-Oxo-Fe2IIICrIII-Glycine Complex
104. Magnetic and electrochemical studies on the series [Cr n Fe3?n (�3-O)(gly)6(H2O)3][NO3]7�xH2O (gly = glycine; n= 0,1,2, or 3) and on the mixed-valence complex [Fe II Fe III 2(�3-O)(gly)6(H2O)3]Cl6
105. Crystal and molecular structure of the trinuclear chromium(III) and iron(III) complex, [Cr2FeO(CH3COO)6(H2O)3]NO3.CH3COOH
106. Vibrational spectra of carboxylate complexes. VII. Partial valence trapping in a trinuclear mixed-valence iron(III,III,II) cluster: vibrational spectra of [Fe3O(OOCCH3)6L3] and related mixed-metal complexes
107. Vibrational spectra of carboxylato complexes—VI. Isotopic substitution in the mixed-metal trinuclear complexes [FeIII2NiIIO(OOCCH3)6L3]
108. Charge shift along the metal-metal bond in molybdenum-tungsten mixed-metal complexes, [M3(.MU.3-O)2(.MU.-CH3COO)6(H2O)3]2+(M3=Mo2W and MoW2) and [MoW(O)2(.MU.-O)2(.MU.-N,N'-edta)]2-.
109. 183W NMR spectra of some di- and tri-nuclear clusters of tungsten(III), (IV), and (V).
110. Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 29. Synthesis of rhenium?tungsten compounds; X-ray crystal structures of [ReW2(�-Br)(�-L)(�-CC6H4Me-4)(�3-CC6H4Me-4)(CO)3(?-C5H5)2](L = CO or O)
111. Chemistry of o-xylidene?metal complexes. Part 3. Tungste o-xylidene complexes derived from tetrachloro(oxo)tungsteh(VI); X-ray crystal structures of [W(CH2C6H4CH2-o)3]�0.5C6H6 and [{W(CH2C6H4CH2-o)2O}2Mg(C4H8O)4]
112. Axially asymmetric metal alkyls. Part 4. Synthesis and X-ray crystal structure of the tungsten(V) metallabicyclic complex [{W[(2-CH2C6H4)2]2O}2Mg(C4H8O)4]�CH2Cl2
113. Oxoalkyls of rhenium-(V) and-(VI). X-Ray crystal structures of (Me4ReO)2Mg(thf)4,[(Me3SiCH2)4ReO]2Mg(thf)2, Re2O3Me6 and Re2O3(CH2SiMe3)6
114. Oxoaryls of rhenium-(V) and -(VI) and osmium(VI). X-Ray crystal structures of dimesityldioxorhenium(VI), tetramesityloxorhenium(VI), and dimesityldioxoosmium(VI)
115. Stoichiometry and kinetics of the acid cleavage of some single-bridged binuclear chromium(III) complexes
116. Early stages of the hydrolysis of chromium(III) in aqueous solution. 1. Characterization of a tetrameric species
117. Early stages of the hydrolysis of chromium(III) in aqueous solution. 2. Kinetics and mechanism of the interconversion between two tetrameric species
118. Early stages of the hydrolysis of chromium(III) in aqueous solution. 3. Kinetics of dimerization of the deprotonated aqua ion
119. Equilibria between di-hydroxo- and hydroxo-bridged dimers of chromium(III)
120. Binuclear Complexes of Chromium(III). I. Thermodynamics and Kinetics of the Equilibrium between mu-Hydroxo and Di-mu-hydroxo Binuclear Complexes of Chromium(III) with Ethylenediamine as a Ligand.