Reactions of a chelated cyclopentadienylcobalt(I) complex with 3,3-disubstituted cyclopropenes: Formation of isoprene, vinylcarbene, and 1-phosphadiene ligands at the metal

Organometallics

Volumn 17, Issue 5, 1998, Pages 893-896

  Foerstner, Jan ^a   Kakoschke, Alf ^a   Stellfeldt, Dirk ^a   Butenschön, Holger ^a   Wartchow, Rudolf ^a  

^a LEIBNIZ UNIVERSITY HANNOVER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000569615     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970851o     Document Type: Article

References (39)

1. Kettenbach, R. T.; Butenschön, H. New J. Chem. 1990, 14, 599.
2. Kettenbach, R. T.; Bonrath, W.; Butenschön, H. Chem. Ber. 1993, 126, 1657.
3. Kettenbach, R. T.; Krüger, C.; Butenschön, H. Angew. Chem. 1992, 104, 1052; Angew. Chem., Int. Ed. Engl. 1992, 31, 1066.
4. Kettenbach, R. T.; Krüger, C.; Butenschön, H. Angew. Chem. 1992, 104, 1052; Angew. Chem., Int. Ed. Engl. 1992, 31, 1066.
5. Foerstner, J.; Kettenbach, R.; Goddard, R.; Butenschön, H. Chem. Ber. 1996, 129, 319.
6. Foerstner, J.; Olbrich, F.; Butenschön, H. Angew. Chem. 1996, 108, 1323; Angew. Chem., Int. Ed. Engl. 1996, 35, 1234.
7. Foerstner, J.; Olbrich, F.; Butenschön, H. Angew. Chem. 1996, 108, 1323; Angew. Chem., Int. Ed. Engl. 1996, 35, 1234.
8. Binger, P.; Schroth, G.; McMeeking, J. Angew. Chem. 1974, 86, 518; Angew. Chem., Int. Ed. Engl. 1974, 13, 465.
9. Binger, P.; Schroth, G.; McMeeking, J. Angew. Chem. 1974, 86, 518; Angew. Chem., Int. Ed. Engl. 1974, 13, 465.
10. Binger, P.; McMeeking, J. Angew. Chem. 1974, 86, 518; Angew. Chem., Int. Ed. Engl. 1974, 13, 466.
11. Binger, P.; McMeeking, J. Angew. Chem. 1974, 86, 518; Angew. Chem., Int. Ed. Engl. 1974, 13, 466.
12. Binger, P.; Müller, P.; Benn, R.; Mynott, R. Angew. Chem. 1989, 101, 647; Angew. Chem., Int. Ed. Engl. 1989, 28, 610.
13. Binger, P.; Müller, P.; Benn, R.; Mynott, R. Angew. Chem. 1989, 101, 647; Angew. Chem., Int. Ed. Engl. 1989, 28, 610.
14. Binger, P.; Buch, H. M. Top. Curr. Chem. 1987, 135, 77.
15. Fischer, H.; Hofmann, J.; Mauz, E. Angew. Chem. 1991, 103, 1013; Angew. Chem., Int. Ed. Engl. 1991, 30, 998.
16. Fischer, H.; Hofmann, J.; Mauz, E. Angew. Chem. 1991, 103, 1013; Angew. Chem., Int. Ed. Engl. 1991, 30, 998.
17. Wadepohl, H.; Pritzkow, H. Angew. Chem. 1987, 99, 132; Angew. Chem., Int. Ed. Engl. 1987, 26, 127.
18. Wadepohl, H.; Pritzkow, H. Angew. Chem. 1987, 99, 132; Angew. Chem., Int. Ed. Engl. 1987, 26, 127.
19. Valeri, T.; Meier, F.; Weiss, E. Chem. Ber. 1988, 121, 1093.
20. Grubbs, R. H.; Miller, S. J.; Fu, G. C. Acc. Chem. Res. 1995, 28, 446.
21. A sample of 3,3-dimethylcyclopropene was kindly provided by Prof. Dr. P. Binger, Universität Kaiserslautern.
22. Binger, P. Synthesis 1974, 190.
23. 6): δ 29.3.
24. Walsh, R.; Untiedt, S.; Stohlmeier, M.; de Meijere, A. Chem. Ber. 1989, 122, 637.
25. Srinivasan, R. J. Chem. Soc. D 1971, 1041.
26. Binger, P. Personal communication.
27. 6): δ 89.9.
28. Baucom, K. B.; Butler, G. B. J. Org. Chem. 1972, 37, 1730.
29. Müller, P. Dissertation, Universität Kaiserslautern, 1989.
30. 3), -66.5 (phosphirene-P). Second crystal fraction: 10 (29 mg, 0.04 mmol, 16%).
31. Haas, J. Dissertation, Universität Kaiserslautern, 1990.
32. Binger, P.; Haas, J.; Herrmann, A. T.; Langhauser, F.; Krüger, C. Angew. Chem. 1991, 103, 316; Angew. Chem., Int. Ed. Engl. 30, 1991, 310.
33. Binger, P.; Haas, J.; Herrmann, A. T.; Langhauser, F.; Krüger, C. Angew. Chem. 1991, 103, 316; Angew. Chem., Int. Ed. Engl. 30, 1991, 310.
34. 3. The crystallographic data (without structure factors) of the structure described in this publication were deposited as supplementary publication no. CCDC 100140 at the Cambridge Crystallography Data Centre. Copies of the data can be obtained with no charge from the following address in Great Britain: The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ (Telefax Int. +1223/336-033. E-mail: deposit@ ccdc.cam.ac.uk).
35. Multiple Bonds and Low Coordination in Phosphorous Chemistry; Regitz, M., Scherer, O. J., Ed.; Georg Thieme Verlag: Stuttgart, 1990.
36. Ajulu, F. A.; Al-Juaid, S. S.; Carmichael, D.; Hitchcock, P. B.; Meidine, M. F.; Nixon, J. F.; Mathey, F.; Huy, N. H. T. J. Organomet. Chem. 1991, 406, C20. We thank one of the reviewers for drawing our attention to this publication.
37. Cheng, P.-T.; Nyburg, S. C. Can. J. Chem. 1972, 50, 912.
38. Nixon, J. F. Chem. Soc. Rev. 1995, 319.
39. Huy, N. H. T.; Ricard, L.; Mathey, F. Organometallics 1988, 7, 1791.