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Volumn 17, Issue 26, 1998, Pages 5728-5745

Enantio- and diastereoselective catalytic carboalumination of 1-alkenes and α,ω-dienes with cationic zirconocenes: Scope and mechanism

Author keywords

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Indexed keywords


EID: 0000553784     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9807811     Document Type: Article
Times cited : (42)

References (69)
  • 1
    • 0001522634 scopus 로고
    • Trost, B. M., Flemming, I., Eds.; Pergamon Press: Oxford
    • Knochel, P. In Comprehensive Organic Synthesis; Trost, B. M., Flemming, I., Eds.; Pergamon Press: Oxford, 1991; Vol. 4; pp 865-911.
    • (1991) Comprehensive Organic Synthesis , vol.4 , pp. 865-911
    • Knochel, P.1
  • 36
    • 85034195481 scopus 로고    scopus 로고
    • note
    • EBTHI = ethylenebis(5,6,7,8-tetrahydroindenyl).
  • 46
    • 85034198633 scopus 로고    scopus 로고
    • note
    • Attempts to use the extremely bulky triphenylsilyl group failed due to the instability of this protecting group under the reaction conditions.
  • 52
    • 85034202048 scopus 로고    scopus 로고
    • note
    • 2 in toluene.
  • 59
    • 85034178887 scopus 로고    scopus 로고
    • note
    • 2, addition of TMA to the catalyst solution in toluene results in separation of the catalyst species as an immiscible oil which remains insoluble throughout the reaction, while in DCE the reaction remains homogeneous. Thus, for these catalysts the differences in reaction rate could be attributed in part to the inhomogeneity of the reaction medium.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.