Addition of OH and alcohols or amines to -C≡N and -CH=CH2 groups of CH2=CHCN coordinated to Cp*Ir(η3-CH2CHCHPh)

Organometallics

Volumn 19, Issue 20, 2000, Pages 4043-4050

  Chin, Chong Shik ^a   Chong, Daesung ^a   Lee, Soojin ^a   Park, Young Ja ^b  

^a Sogang University   (South Korea)

^b Sookmyung Women's University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000546163     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0002881     Document Type: Article

References (31)

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29. 2).
30. It has been suggested that amido complexes exist mainly as the enol form isomers, M-N=C(OH)R, in a polar solvent such as acetone, while the keto form isomer, M-NHCOR, is the predominant species in a nonpolar solvent such as benzene. See refs 3 and 6c.
31. Bergman, R. G.; Golden, J. T.; Peterson, T. H. Organometallics 1999, 18, 2005, and see references therein for related NMR spectral data.