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We consider the ΔH and ΔS contribution due to competitive DMF binding to be small because DMF binding to a number of NKAP complexes is not significantly enhanced (Kdmf= 5), see
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Recently, questions have been raised about the alleged distal steric effects on Fe—CO; after all, the distal histidine could be quite mobile Ray, G. B.; Li, X.-Y.; Ibers, J. A.: Sessler, J. L.; Spiro, T. G. J. Am. Chem. Soc. 1994, 116, 162
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