Long-Lived Reactive Excited States of Zero-Valent Phosphine, Phosphite, and Arsine Complexes of Nickel, Palladium, and Platinum

Journal of the American Chemical Society

Volumn 107, Issue 23, 1985, Pages 6718-6719

  Caspar, Jonathan V ^a  

^a DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000520608     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00309a055     Document Type: Article

References (11)

1. 1b (b) Ziolo, R. F.; Lipton, S.; Bori, Z. J. Chem. Soc., Chem. Commun. 1970, 1124.
2. All complexes were prepared by literature methods, (a) Kuran, W.; Musco, A. Inorg. Chim. Acta 1975, 12, 187. (b) Ittel, S. D. Inorg. Synth. 1976, 17, 117.
3. Stern, E. W.; Maples, P. K. J. Catal. 1972, 27, 120.
4. (a) Manojlovic-Muir, L.; Muir, K. W. J. Chem. Soc., Chem. Commun. 1982, 1155. (b) Albano, V.; Bellon, P. L.; Scatturin, V. J. Chem. Soc., Chem. Commun. 1966, 507.
5. (a) Mann, B. E.; Musco, A. J. Chem. Soc., Dalton Trans. 1975, 1673. (b) Tolman, C. A.; Seidel, W. C.; Gerlach, D. H. J. Am. Chem. Soc. 1972, 94, 2669.
6. Caspar, J. V., unpublished results. For calculational methods, see: (a) Pensak, D. A.; McKinney, R. J. Inorg. Chem. 1979, 18, 3407. (b) McKinney, R. J.; Pensak, D. A. Inorg. Chem. 1979, 18, 3413.
7. (a) Geoffroy, G. L.; Gray, H. B.; Hammond, G. S.; Wrighton, M. S. J. Am. Chem. Soc. 1974, 96, 3105, (b) Andrews, L. J. Inorg. Chem. 1978, 17, 3180. (c) Fordyce, W. A.; Crosby, G. A. Inorg. Chem. 1982, 21, 1455.
8. 11bWe believe that this reaction was in fact proceeding photochemically under room light. After 48 h in the dark we find no detectable thermal reaction between the dimer and methylene chloride. (b) Balch, A. L.; Hunt, C. T.; Lee, C.; Olmstead, M. M.; Farr, J. P. J. Am. Chem. Soc. 1981, 103, 3764.
9. 12b(b) Coulson, D. R. J. Chem. Soc., Chem. Commun. 1968, 1530.
10. (a) Heck, R. F. Pure Appl. Chem. 1978, 50, 691. (b) Maitlis, P. M. “The Organic Chemistry of Palladium”; Academic Press: New York, 1971.
11. (a) Kramer, A. V.; Labinger, J. A.; Bradley, J. S.; Osborn, J. A. J. Am. Chem. Soc. 1974, 96, 7145. (b) Lappert, M. F.; Lednor, P. W. J. Chem. Soc., Chem. Commun. 1973, 948.