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Volumn 2, Issue 15, 2000, Pages 2201-2204

Kinetic isotope effects for the C-H activation step in phase-transfer halogenations of alkanes

Author keywords

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Indexed keywords


EID: 0000515520     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0059347     Document Type: Article
Times cited : (20)

References (37)
  • 22
    • 85037496831 scopus 로고    scopus 로고
    • note
    • -1.
  • 28
    • 85037509123 scopus 로고    scopus 로고
    • note
    • 2 and 3 mL of NaOH (aq. 50%). In the case of bromination, the results were confirmed by experiments in separate vials Determination of the relative concentrations of deuterated and nondeuterated products were carried out by GC/MS analysis (HP5890 Series II GC column HP Ultral (50 m × 0.2 mm × 0.33 mm film: cross-linked methyl silicone with HP5971A mass selective detector) by mass selective integration.
  • 29
    • 85037507637 scopus 로고    scopus 로고
    • note
    • Calibration of the relative abundance of deuterated and nondeuterated products led to scaling factors of 1.15 and 1.18 for bromination and iodination of 3 vs 4, respectively; the scaling factors for the adamantane reactions were 1.0.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.