Synthesis and Characterization of Na6Cd7S10: A New Framework Sulfide with 1-D Channels Containing 12- and 16-Member Rings and a Sulfide Anion in an Umbrella-like Geometry

Chemistry of Materials

Volumn 8, Issue 7, 1996, Pages 1350-1352

  Axtell III, Enos A ^a   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000514834     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm9506060     Document Type: Article

References (26)

1. (a) Ozin, G. A. Adv. Mater. 1992, 4, 612-649.
2. (b) Reed, M. A. Sci. Am. 1993, 118-123.
3. (c) Axtell, E. A., III; Liao, J.-H.; Pikramenou, Z.; Park, Y.; Kanatzidis, M. G. J. Am. Chem. Soc. 1993, 115, 12191-2.
4. Ishihara, T.; Takahashi, J.; Goto, T. Phys. Rev. B 1990, 42, 11099-11107.
5. (b) Papavassiliou, G. C.; Patsis, A. P.; Lagouvardos, D. J.; Koutselas, L. B. Synth. Met. 1993, 55-57, 3889-3894.
6. (c) Hong, X.; Ishihara, T.; Nurmikko, A. V. Phys. Rev. B 1992, 45, 6961-6964.
7. (d) Ishihara, T.; Takahashi, J.; Goto, T. Solid State Commun. 1989, 69, 933-936.
8. (e) Papavassiliou, G. C.; Koutselas, J. B.; Lagouvardos, D. J. Z. Naturforsch. 1993, 48b, 1013-1014.
9. (f) Vincent, B. R.; Robertson, K. N.; Camaron, T. S.; Knop, O. Can. J. Chem. 1987, 65, 1042-1046.
10. (g) Nagapetyan, S. S.; Dolzhenko, Yu. I.; Arakelova, E. R.; Koshkin, V. M.; Struchkov, Yu. T.; Shklover, V. E. Russ. J. Inorg. Chem. 1988, 33, 1614-1618.
11. (h) Poglitsch, A.; Weber, D. J. Chem. Phys. 1987, 87, 6373-6378.
12. (i) Xu, C.-Q.; Sakakura, H.; Kondo, T.; Takeyama, S.; Miura, N.; Takahashi, Y.; Kumata, K.; Ito, R. Solid State Commun. 1991, 79, 249-253.
13. (j) Xu, C.-Q.; Kondo, T.; Sakakura, H.; Kumata, K.; Takahashi, Y.; Ito, R. Solid State Commun. 1991, 79, 245-248.
14. (k) Era, M.; Morimoto, S.; Tsutsui, T.; Saito, S. Synth. Met. 1995, 71, 2013-2014.
15. Axtell, III, E. A.; Liao, J.-H.; Kanatzidis, M. G. Chem. Eur. J., in press.
16. Klepp, K. O.; Bronger, W. Rev. Chim. Miner. 1983, 20(4-5), 682-688.
17. Polyvyannyi, I. R.; Lata, V. A.; Ivakina, L. P.; Antonyuk, V. I. Russ. J. Inorg. Chem. 1981, 26(4), 561-563.
18. Ansari, M. A.; Ibers, J. A. J. Solid State Chem. 1993, 103, 293-297.
19. 7d was applied to all data, (a) D. K. Smith, M. C. Nichols, M. E. Zolensky, POWD10: A FORTRAN IV Program for Calculating X-ray Powder Diffraction Patterns, Version 10; Pennsylvania State University, 1983. (b) G. M. Sheldrick, In Crystallographic Computing 3; Sheldrick, G. M., Kruger, C., Doddard, R., Eds.; Oxford University Press: Oxford, England, 1985; pp 175-189. (c) TEXSAN: Single Crystal Structural Analysis Software, Version 5.0; Molecular Structure Corp.: The Woodlands, TX 77381, 1981. (d) Walker, N; Stuart, D. Acta Crystallogr. 1983, 39A, 158.
20. 7d was applied to all data, (a) D. K. Smith, M. C. Nichols, M. E. Zolensky, POWD10: A FORTRAN IV Program for Calculating X-ray Powder Diffraction Patterns, Version 10; Pennsylvania State University, 1983. (b) G. M. Sheldrick, In Crystallographic Computing 3; Sheldrick, G. M., Kruger, C., Doddard, R., Eds.; Oxford University Press: Oxford, England, 1985; pp 175-189. (c) TEXSAN: Single Crystal Structural Analysis Software, Version 5.0; Molecular Structure Corp.: The Woodlands, TX 77381, 1981. (d) Walker, N; Stuart, D. Acta Crystallogr. 1983, 39A, 158.
21. 7d was applied to all data, (a) D. K. Smith, M. C. Nichols, M. E. Zolensky, POWD10: A FORTRAN IV Program for Calculating X-ray Powder Diffraction Patterns, Version 10; Pennsylvania State University, 1983. (b) G. M. Sheldrick, In Crystallographic Computing 3; Sheldrick, G. M., Kruger, C., Doddard, R., Eds.; Oxford University Press: Oxford, England, 1985; pp 175-189. (c) TEXSAN: Single Crystal Structural Analysis Software, Version 5.0; Molecular Structure Corp.: The Woodlands, TX 77381, 1981. (d) Walker, N; Stuart, D. Acta Crystallogr. 1983, 39A, 158.
22. 7d was applied to all data, (a) D. K. Smith, M. C. Nichols, M. E. Zolensky, POWD10: A FORTRAN IV Program for Calculating X-ray Powder Diffraction Patterns, Version 10; Pennsylvania State University, 1983. (b) G. M. Sheldrick, In Crystallographic Computing 3; Sheldrick, G. M., Kruger, C., Doddard, R., Eds.; Oxford University Press: Oxford, England, 1985; pp 175-189. (c) TEXSAN: Single Crystal Structural Analysis Software, Version 5.0; Molecular Structure Corp.: The Woodlands, TX 77381, 1981. (d) Walker, N; Stuart, D. Acta Crystallogr. 1983, 39A, 158.
23. Preliminary X-ray photographic examination of crystals of this compound did not reveal signs of a superstructure which may be due to Cd vacancy ordering. An electron diffraction study would be more appropriate to address this issue.
24. Troger, F. J. Am. Mineral. 1966, 51, 890-894.
25. 2 = 0.
26. Photoluminescence spectra were obtained on a Spex Fluorolog-2, Model F111A1 spectrofluorometer according to procedures reported in ref 3.