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Volumn 61, Issue 5, 2000, Pages 6019-6022

Fluid-fluid transitions of hard spheres with a very-short-range attraction

Author keywords

[No Author keywords available]

Indexed keywords

CLOSE PACKING; EXPERIMENTAL SYSTEM; HARD SPHERES; MONO-DISPERSE PARTICLES; SHORT-RANGE ATTRACTION; SPHERE DIAMETER;

EID: 0000509422     PISSN: 1063651X     EISSN: None     Source Type: Journal    
DOI: 10.1103/PhysRevE.61.6019     Document Type: Article
Times cited : (7)

References (22)
  • 1
    • 0004165166 scopus 로고    scopus 로고
    • Princeton University Press, Princeton, NJ
    • P. G. Debenedetti, Metastable Liquids (Princeton University Press, Princeton, NJ, 1996).
    • (1996) Metastable Liquids
    • Debenedetti, P.G.1
  • 8
    • 85036425153 scopus 로고    scopus 로고
    • By construction, Speedy’s entropy for hard spheres 7 has a second-order phase transition when the value of (Formula presented) obtained by maximizing the entropy equals the random-close-packing volume fraction. He assumes that beyond the kinetic glass transition observed in experiment is an ideal glass transition that is a true thermoynamic transition. It is an open question whether this is correct or not. Our free energy also has such a phase transition because it contains Speedy’s entropy. This transition occurs at densities above the fluid-fluid transition and is not shown in our figures
    • By construction, Speedy’s entropy for hard spheres 7 has a second-order phase transition when the value of (Formula presented) obtained by maximizing the entropy equals the random-close-packing volume fraction. He assumes that beyond the kinetic glass transition observed in experiment is an ideal glass transition that is a true thermoynamic transition. It is an open question whether this is correct or not. Our free energy also has such a phase transition because it contains Speedy’s entropy. This transition occurs at densities above the fluid-fluid transition and is not shown in our figures.
  • 10
    • 85036134454 scopus 로고    scopus 로고
    • (unpublished)
    • R. P. Sear (unpublished).
    • Sear, R.P.1
  • 20
    • 85036401453 scopus 로고    scopus 로고
    • The calculations presented here implicitly rely on a constraint that eliminates the crystalline phase at (Formula presented); the PY approximation relies on a constraint that eliminates the crystal at (Formula presented). This constraint must eliminate the crystalline clusters, which have divergent contributions to the virial expansion at finite (Formula presented)
    • The calculations presented here implicitly rely on a constraint that eliminates the crystalline phase at (Formula presented); the PY approximation relies on a constraint that eliminates the crystal at (Formula presented). This constraint must eliminate the crystalline clusters, which have divergent contributions to the virial expansion at finite (Formula presented).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.