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1
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0004165166
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Princeton University Press, Princeton, NJ
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P. G. Debenedetti, Metastable Liquids (Princeton University Press, Princeton, NJ, 1996).
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(1996)
Metastable Liquids
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Debenedetti, P.G.1
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4
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85036183620
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J. P. Hansen, D. Levesque, J. Zinn-Justin, North-Holland, Amsterdam
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P. N. Pusey, in Liquids, Freezing and Glass Transitions Proceedings of the Les Houches Summer School of Theoretical Physics, edited by J. P. Hansen, D. Levesque, and J. Zinn-Justin (North-Holland, Amsterdam, 1991).
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(1991)
Liquids, Freezing and Glass Transitions Proceedings of the Les Houches Summer School of Theoretical Physics
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Pusey, P.N.1
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8
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85036425153
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By construction, Speedy’s entropy for hard spheres 7 has a second-order phase transition when the value of (Formula presented) obtained by maximizing the entropy equals the random-close-packing volume fraction. He assumes that beyond the kinetic glass transition observed in experiment is an ideal glass transition that is a true thermoynamic transition. It is an open question whether this is correct or not. Our free energy also has such a phase transition because it contains Speedy’s entropy. This transition occurs at densities above the fluid-fluid transition and is not shown in our figures
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By construction, Speedy’s entropy for hard spheres 7 has a second-order phase transition when the value of (Formula presented) obtained by maximizing the entropy equals the random-close-packing volume fraction. He assumes that beyond the kinetic glass transition observed in experiment is an ideal glass transition that is a true thermoynamic transition. It is an open question whether this is correct or not. Our free energy also has such a phase transition because it contains Speedy’s entropy. This transition occurs at densities above the fluid-fluid transition and is not shown in our figures.
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10
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85036134454
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(unpublished)
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R. P. Sear (unpublished).
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Sear, R.P.1
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13
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84914186249
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D. Henderson, E. Waisman, J. L. Lebowitz, and L. Blum, Mol. Phys. 35, 241 (1978).
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(1978)
Mol. Phys.
, vol.35
, pp. 241
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Henderson, D.1
Waisman, E.2
Lebowitz, J.L.3
Blum, L.4
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14
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0003644127
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Academic Press, London, Chap. 6
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J. P. Hansen and I. R. McDonald, Theory of Simple Liquids, 2nd ed. (Academic Press, London, 1986), Chap. 6.
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(1986)
Theory of Simple Liquids, 2nd ed.
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Hansen, J.P.1
McDonald, I.R.2
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20
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85036401453
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The calculations presented here implicitly rely on a constraint that eliminates the crystalline phase at (Formula presented); the PY approximation relies on a constraint that eliminates the crystal at (Formula presented). This constraint must eliminate the crystalline clusters, which have divergent contributions to the virial expansion at finite (Formula presented)
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The calculations presented here implicitly rely on a constraint that eliminates the crystalline phase at (Formula presented); the PY approximation relies on a constraint that eliminates the crystal at (Formula presented). This constraint must eliminate the crystalline clusters, which have divergent contributions to the virial expansion at finite (Formula presented).
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