Synthesis and spectroscopic characterization of new Cu(I) complexes containing triaryl-, tricycloalkylphosphines and heterocyclic anionic or neutral N-donor ligands. Crystal and molecular structure of [ (Cy3P)2(pzH)Cu]ClO4·CH3OH (Cy = cyclohexyl, pzH = pyrazole)

Inorganica Chimica Acta

Volumn 249, Issue 2, 1996, Pages 215-229

  Pettinari, Claudio ^a   Marchetti, Fabio ^a   Polimante, Roberta ^a   Cingolani, Augusto ^a   Portalone, Gustavo ^b   Colapietro, Marcello ^b  

^a UNIVERSITY OF CAMERINO   (Italy)

^b SAPIENZA UNIVERSITY OF ROME   (Italy)

Author keywords

Copper complexes; Crystal structures; N ligand complexes; Tertiary phosphine complexes

Indexed keywords

CHELATION; CHLORINE COMPOUNDS; COMPLEXATION; COPPER METALLOGRAPHY; CRYSTAL STRUCTURE; ETHERS; GEOMETRY; HYDROGEN; HYDROGEN BONDS; LIGANDS; METHANE; METHANOL; MOLECULES; PHOSPHORUS COMPOUNDS; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL);

1 ,10-PHENANTHROLINE; COPPER COMPLEXES; CRYSTAL AND MOLECULAR STRUCTURE; N LIGANDS; SINGLE CRYSTAL X-RAY DIFFRACTION; SPECTROSCOPIC CHARACTERIZATION; TERTIARY PHOSPHINES; TRIPHENYL PHOSPHINES;

COPPER COMPOUNDS;

EID: 0000505502     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/0020-1693(96)05101-8     Document Type: Article

References (69)

1. G. La Monica, M.A. Angaroni and G.A. Ardizzoia, J. Organomet. Chem., 348 (1988) 279; G.A. Ardizzoia, G. La Monica, M.A. Angaroni and F. Cariati, Inorg. Chim. Acta, 158 (1989) 159; G. La Monica, M.A. Angaroni, F. Cariati and S. Cenini, Inorg. Chim. Acta, 143 (1988) 239.
2. G. La Monica, M.A. Angaroni and G.A. Ardizzoia, J. Organomet. Chem., 348 (1988) 279; G.A. Ardizzoia, G. La Monica, M.A. Angaroni and F. Cariati, Inorg. Chim. Acta, 158 (1989) 159; G. La Monica, M.A. Angaroni, F. Cariati and S. Cenini, Inorg. Chim. Acta, 143 (1988) 239.
3. G. La Monica, M.A. Angaroni and G.A. Ardizzoia, J. Organomet. Chem., 348 (1988) 279; G.A. Ardizzoia, G. La Monica, M.A. Angaroni and F. Cariati, Inorg. Chim. Acta, 158 (1989) 159; G. La Monica, M.A. Angaroni, F. Cariati and S. Cenini, Inorg. Chim. Acta, 143 (1988) 239.
4. H.B. Gray and B.I. Solomon, in T.G. Spiro (ed.), Copper Proteins, Wiley-Interscience, New York, 1981, Ch. I; H. Sigel (ed.), Metal Ions in Biological Systems, Vol. 13, Copper Proteins, Marcel Dekker, New York, 1981.
5. H.B. Gray and B.I. Solomon, in T.G. Spiro (ed.), Copper Proteins, Wiley-Interscience, New York, 1981, Ch. I; H. Sigel (ed.), Metal Ions in Biological Systems, Vol. 13, Copper Proteins, Marcel Dekker, New York, 1981.
6. M.J. Hampden-Smith, T.T. Kodas, M. Paffett, J.D. Farr and H.-K. Shin, Chem. Mater., 2 (1990) 636; J. Farkas, M.J. Hampden-Smith and T.T. Kodas, J. Phys. Chem., 98 (1994) 6753.
7. M.J. Hampden-Smith, T.T. Kodas, M. Paffett, J.D. Farr and H.-K. Shin, Chem. Mater., 2 (1990) 636; J. Farkas, M.J. Hampden-Smith and T.T. Kodas, J. Phys. Chem., 98 (1994) 6753.
8. F. Bonati, A. Cingolani, G. Gioia Lobbia, D. Leonesi, A. Lorenzotti and C. Pettinari, Gazz. Chim. Ital., 120 (1990) 341.
9. C. Pettinari, G. Gioia Lobbia, G. Sclavi, D. Leonesi, M. Colapietro and G. Portalone, Polyhedron, 14 (1995) 1709.
10. J.T. Gill, J.J. Mayerle, P.S. Welcker, D.F. Lewis, D.A. Ucko, D.J. Barton and D. Stovens, Inorg. Chem., 15 (1976) 155.
11. C.A. Tolman, J. Am. Chem. Soc., 92 (1970) 2956; Chem. Rev., 77 (1977) 313.
12. C.A. Tolman, J. Am. Chem. Soc., 92 (1970) 2956; Chem. Rev., 77 (1977) 313.
13. M.R. Grimmett, Imidazoles and their benzo derivatives: (i) Structure, in A.R. Katritzky and C.W. Rees (eds. in chief), and K.T. Potts (ed.), Comprehensive Heterocyclic Chemistry, Vol. 5, Part 4A, Pergamon, Oxford, 1984, p. 345.
14. G. Gioia Lobbia and F. Bonati, Synth. React. Inorg. Met.-Org. Chem., 551 (1988) 551.
15. A. Lorenzotti, A. Cingolani, G. Gioia Lobbia and D. Leonesi, Gazz. Chim. Ital., 117 (1987) 191; D. Leonesi, A. Cingolani, G. Gioia Lobbia, A. Lorenzotti and F. Bonati, Gazz. Chim. Ital., 117 (1987) 491.
16. A. Lorenzotti, A. Cingolani, G. Gioia Lobbia and D. Leonesi, Gazz. Chim. Ital., 117 (1987) 191; D. Leonesi, A. Cingolani, G. Gioia Lobbia, A. Lorenzotti and F. Bonati, Gazz. Chim. Ital., 117 (1987) 491.
17. F.A. Cotton and D.M.L. Goodgame, J. Chem. Soc., (1960) 5267.
18. R.J. Restivo, A. Costin, G. Ferguson and A.J. Carty, Can J. Chem., 53 (1975) 1949.
19. W.A. Anderson, A.J. Carty, G.J. Palenik and G. Schreiber, Can. J. Chem., 49 (1971) 761.
20. D.M.L. Goodgame, M. Goodgame, P.J. Hayward and G.W. Rayner-Canham, Inorg. Chem., 7 (1968) 2447.
21. W.C. Wolsey, J. Chem. Educ., 55 (1973) A355.
22. M. Colapietro, L. Barba, C. Marciante, A. Pifferi and R. Spagna, personal communication.
23. International Tables for X-ray Crystallography, Vol. IV, Kynoch, Birmingham, UK, 1974, pp. 99-149.
24. M. Camalli, D. Capitani, G. Cascarano, S. Cerrini, C. Giacovazzo and R. Spagna, Ital. Patent No. 35403c/86; SIRCAOS USERGUIDE, Istituto di Strutturistica Chimica CNR.
25. M. Camalli, D. Capitani, G. Cascarano, S. Cerrini, C. Giacovazzo and R. Spagna, Ital. Patent No. 35403c/86; SIRCAOS USERGUIDE, Istituto di Strutturistica Chimica CNR.
26. J. Zukerman-Schpector, E.E. Castellano, A.E. Mauro and M.R. Roveri, Acta Crystallogr., Sect. C, 42 (1986) 302; L.M. Engelhardt, P.C. Healy, J.D. Kildea and A.H. White, Aust. J. Chem., 42 (1989) 913; 44 (1991) 729; G.A. Bowmaker, J.V. Hanna, R.D. Hart, P.C. Healy and A.H. White, J. Chem. Soc., Dalton Trans., (1994) 2621.
27. J. Zukerman-Schpector, E.E. Castellano, A.E. Mauro and M.R. Roveri, Acta Crystallogr., Sect. C, 42 (1986) 302; L.M. Engelhardt, P.C. Healy, J.D. Kildea and A.H. White, Aust. J. Chem., 42 (1989) 913; 44 (1991) 729; G.A. Bowmaker, J.V. Hanna, R.D. Hart, P.C. Healy and A.H. White, J. Chem. Soc., Dalton Trans., (1994) 2621.
28. J. Zukerman-Schpector, E.E. Castellano, A.E. Mauro and M.R. Roveri, Acta Crystallogr., Sect. C, 42 (1986) 302; L.M. Engelhardt, P.C. Healy, J.D. Kildea and A.H. White, Aust. J. Chem., 42 (1989) 913; 44 (1991) 729; G.A. Bowmaker, J.V. Hanna, R.D. Hart, P.C. Healy and A.H. White, J. Chem. Soc., Dalton Trans., (1994) 2621.
29. J. Zukerman-Schpector, E.E. Castellano, A.E. Mauro and M.R. Roveri, Acta Crystallogr., Sect. C, 42 (1986) 302; L.M. Engelhardt, P.C. Healy, J.D. Kildea and A.H. White, Aust. J. Chem., 42 (1989) 913; 44 (1991) 729; G.A. Bowmaker, J.V. Hanna, R.D. Hart, P.C. Healy and A.H. White, J. Chem. Soc., Dalton Trans., (1994) 2621.
30. C. Pettinari, A. Cingolani and B. Bovio, Polyhedron, 15 (1996) 115.
31. M.M. Rahman, H.-Y. Liu, K. Eriks, A. Prock and W.P. Giering, Organometallics, 8 (1989) 1.
32. D. Leonesi, A. Lorenzotti, A. Cingolani and F. Bonati, Gazz. Chim. Ital., 111 (1981) 483; A. Lorenzotti, A. Cingolani, D. Leonesi and F. Bonati, Inorg. Chim. Acta, 89 (1984) 113; J.G.A. Luijten and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 82 (1963) 1181; J.G.A. Luijten, M.J. Janssen and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 81 (1962) 202; R. Gassend, J.C. Maire and J.C. Pommier, J. Organomet. Chem., 132 (1977) 69.
33. D. Leonesi, A. Lorenzotti, A. Cingolani and F. Bonati, Gazz. Chim. Ital., 111 (1981) 483; A. Lorenzotti, A. Cingolani, D. Leonesi and F. Bonati, Inorg. Chim. Acta, 89 (1984) 113; J.G.A. Luijten and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 82 (1963) 1181; J.G.A. Luijten, M.J. Janssen and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 81 (1962) 202; R. Gassend, J.C. Maire and J.C. Pommier, J. Organomet. Chem., 132 (1977) 69.
34. D. Leonesi, A. Lorenzotti, A. Cingolani and F. Bonati, Gazz. Chim. Ital., 111 (1981) 483; A. Lorenzotti, A. Cingolani, D. Leonesi and F. Bonati, Inorg. Chim. Acta, 89 (1984) 113; J.G.A. Luijten and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 82 (1963) 1181; J.G.A. Luijten, M.J. Janssen and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 81 (1962) 202; R. Gassend, J.C. Maire and J.C. Pommier, J. Organomet. Chem., 132 (1977) 69.
35. D. Leonesi, A. Lorenzotti, A. Cingolani and F. Bonati, Gazz. Chim. Ital., 111 (1981) 483; A. Lorenzotti, A. Cingolani, D. Leonesi and F. Bonati, Inorg. Chim. Acta, 89 (1984) 113; J.G.A. Luijten and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 82 (1963) 1181; J.G.A. Luijten, M.J. Janssen and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 81 (1962) 202; R. Gassend, J.C. Maire and J.C. Pommier, J. Organomet. Chem., 132 (1977) 69.
36. D. Leonesi, A. Lorenzotti, A. Cingolani and F. Bonati, Gazz. Chim. Ital., 111 (1981) 483; A. Lorenzotti, A. Cingolani, D. Leonesi and F. Bonati, Inorg. Chim. Acta, 89 (1984) 113; J.G.A. Luijten and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 82 (1963) 1181; J.G.A. Luijten, M.J. Janssen and G.J.M. Van der Kerk, Recl. Trav. Chem. Pays-Bas, 81 (1962) 202; R. Gassend, J.C. Maire and J.C. Pommier, J. Organomet. Chem., 132 (1977) 69.
37. L.M. Engeihardt, C. Pakawatchai, A.H. White and P.C. Healy, J. Chem. Soc., Dalton Trans., (1985) 125.
38. K. Nakamoto, in K. Nakamoto (ed.), Infrared and Roman Spectra of Inorganic and Coordination Compounds, Wiley-Interscience, New York, 4th edn., 1986; J.G. Vos and W.L. Groeneveld, Inorg. Chim. Acta, 24 (1977) 123.
39. K. Nakamoto, in K. Nakamoto (ed.), Infrared and Roman Spectra of Inorganic and Coordination Compounds, Wiley-Interscience, New York, 4th edn., 1986; J.G. Vos and W.L. Groeneveld, Inorg. Chim. Acta, 24 (1977) 123.
40. H. Okkersen, W.L. Groeneveld and J. Reedijk, Recl. Trav. Chim. Pays-Bas, 92 (1973) 945.
41. M.R. Rosenthal, J. Chem. Educ., 50 (1973) 331.
42. G.A. Bowmaker and D. A Rogers, J. Chem. Soc., Dalton Trans., (1984) 1249.
43. K. Nakamoto, Coordination compounds, in Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley-Interscience, New York, 4th edn., 1986, pp. 328-331.
44. K. Shobatake, C. Postmus, J.R. Ferraro and K. Nakamoto, Appl. Spectrosc., 23 (1969) 12.
45. J Bradbury, K.P. Forest, R.H. Nuttall and S.W. A Sharp, Spectrochim. Acta, 23 (1967) 2701.
46. J.G. Verkade, Coord. Chem. Rev., 9 (1972) 1.
47. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley-Interscience, New York, 4th edn., 1986, pp. 201-220.
48. R.C.R. Pozharskii, A.D. Garnovskii and A.M. Simonov, Russ. Chem. Rev. (Engl. Transl.), 35 (1966) 122.
49. E.W. Abel, R.A.N. Mc Lean and I.H. Sabherwal, J. Chem. Soc. A, (1969) 133.
50. M.R. Grimmett, Adv. Heterocycl. Chem., 11 (1970) 1.
51. M.R. Grimmett, Imidazoles and their benzo derivatives: (i) Structure, in A.R. Katritzky and C.W. Rees (eds. in chief), and K.T. Potts (ed.), Comprehensive Heterocyclic Chemistry, Vol. 5, Part 4A, Pergamon, Oxford, 1984, p. 356.
52. N.F. Borkett and M.I. Bruce, J. Organomet. Chem., 65 (1974) C51; R. Gassend, J.C. Marie and J.C. Pommier, J. Organomet. Chem., 132 (1977) 69; M.A. Angaroni, G.A. Ardizzoia, T. Beringhelli, G. D'Alfonso, G. La Monica, N. Masvciocchi and M. Moret, J. Organomet. Chem., 363 (1989) 409.
53. N.F. Borkett and M.I. Bruce, J. Organomet. Chem., 65 (1974) C51; R. Gassend, J.C. Marie and J.C. Pommier, J. Organomet. Chem., 132 (1977) 69; M.A. Angaroni, G.A. Ardizzoia, T. Beringhelli, G. D'Alfonso, G. La Monica, N. Masvciocchi and M. Moret, J. Organomet. Chem., 363 (1989) 409.
54. N.F. Borkett and M.I. Bruce, J. Organomet. Chem., 65 (1974) C51; R. Gassend, J.C. Marie and J.C. Pommier, J. Organomet. Chem., 132 (1977) 69; M.A. Angaroni, G.A. Ardizzoia, T. Beringhelli, G. D'Alfonso, G. La Monica, N. Masvciocchi and M. Moret, J. Organomet. Chem., 363 (1989) 409.
55. S.J. Berners-Price and P.J. Sadler, Inorg. Chem., 25 (1986) 3822, and Refs. therein.
56. S. Attar and J. Malito, Polyhedron, 11 (1992) 2409.
57. A.M. Leiva, L. Rivera and B. Loeb, Polyhedron, 10 (1991) 347.
58. H.-K. Shin, M.J. Hampden-Smith, E.N. Duesler and T. Kodas, Can. J. Chem., 70 (1992) 2954.
59. T.N. Sorrell and D.J. Jameson, J. Am. Chem. Soc., 105 (1983) 6013; L.M. Engelhardt, C. Pakawatchai, A.H. White and P.C. Healy, J. Chem. Soc., Dalton Trans., (1985) 125.
60. T.N. Sorrell and D.J. Jameson, J. Am. Chem. Soc., 105 (1983) 6013; L.M. Engelhardt, C. Pakawatchai, A.H. White and P.C. Healy, J. Chem. Soc., Dalton Trans., (1985) 125.
61. [43 ] R. Hamalainen, U. Turpeinen, M. Ahlgreen and T. Raikas, Finn. Chem. Lett., (1978) 199; R. Hamalainen, M. Ahlgreen, U. Turpeinen and T. Raikas, Cryst. Struct. Commun., 8 (1979) 75; G. Dessy and V. Fares, Cryst. Struct. Commun., 8 (1979) 507.
62. [43 ] R. Hamalainen, U. Turpeinen, M. Ahlgreen and T. Raikas, Finn. Chem. Lett., (1978) 199; R. Hamalainen, M. Ahlgreen, U. Turpeinen and T. Raikas, Cryst. Struct. Commun., 8 (1979) 75; G. Dessy and V. Fares, Cryst. Struct. Commun., 8 (1979) 507.
63. [43 ] R. Hamalainen, U. Turpeinen, M. Ahlgreen and T. Raikas, Finn. Chem. Lett., (1978) 199; R. Hamalainen, M. Ahlgreen, U. Turpeinen and T. Raikas, Cryst. Struct. Commun., 8 (1979) 75; G. Dessy and V. Fares, Cryst. Struct. Commun., 8 (1979) 507.
64. B.E. Gree, C.H.L. Kennard, G. Smith, B.D. James and A.H. White, Acta Crystallogr., Sect. C, 40 (1984) 426.
65. L.M. Engelhardt, C. Pakawatchai, A.H. White and P.C. Healy, J. Chem. Soc., Dalton Trans., (1985) 125.
66. F. Bonati, Gazz. Chim. Ital., 119 (1989) 291.
67. J.R. Kirkhhoff, D.R. McMillin, W.R. Robinson, D.R. Powell, A.T. McKenzie and S. Chen, Inorg. Chem., 24 (1985) 3928.
68. P. Karagiannidis, P. Aslanidis, S. Papastefanou, D. Mentzafos, A. Hountas and A. Terzis, Inorg. Chim. Acta, 156 (1989) 265.
69. S.J. Lippard and G.J. Palenik, Inorg. Chem., 10 (1971) 1322.