The Gas-Phase Cannizzaro Disproportionation Reactions of Benzaldehyde and Pivaldehyde

Journal of Organic Chemistry

Volumn 62, Issue 12, 1997, Pages 3931-3937

  Sheldon, John C ^a   Bowie, John H ^a   Dua, Suresh ^a   Smith, Jacob D ^b   O'Hair, Richard A J ^b  

^a UNIVERSITY OF ADELAIDE   (Australia)

^b KANSAS STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000502053     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9520598     Document Type: Article

References (46)

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15. - (these results are similar to data shown in Tables 1 and 2 for the analogous reactions with benzaldehyde and pivaldehyde).
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21. -1 (cf. also footnote 22)].
22. 8
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27. -/He/t-BuCHO] in the FA and that this process is more efficient than deprotonation of pivaldehyde to form the homoenolate anion. DePuy C. H. Unpublished observations, cited in DePuy, C. H.; Grabowski, J. J.; Bierbaum, V. M.; Ingemann, S.; Nibbering, N. M. M. J. Am. Chem. Soc. 1985, 107, 1093.
28. -) ion is a secondary product, since its abundance extrapolates to zero at zero flow rate.
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32. -1 respectively (primary data from ref 11).
33. 18O (see fable 2 for full details).
34. -1.
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37. - and 2,2-dimethylcyelopropanone, since this reaction cannot lead directly to the pivalate anion.
38. 2..
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