Steric acceleration of dynamic processes in 1,2-dicyclooctatetraenylbenzene

Organic Letters

Volumn 1, Issue 4, 1999, Pages 565-567

  Staley, Stuart W ^a   Kehlbeck, Joanne D ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000500527     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol990638j     Document Type: Article

References (12)

1. Review: Raquette, L. A. Acc. Chem. Res. 1993, 26, 57.
2. Staley, S. W.; Kehlbeck, J. D.; Grimm, R. A.; Sablosky, R. A.; Boman, P.; Eliasson, B. J. Am. Chem. Soc. 1998, 120, 9793.
3. 18: C, 93.58; H, 6.42. Found: C, 93.66; H, 6.36. Attempts to reduce 3 with potassium, sodium, or lithium as described in ref 2 were unsuccessful owing to rapid decomposition of the sample.
4. r.i. can be reliably calculated at the HF level of theory: Karadakov, P. B.; Gerratt, J.; Cooper, D. L.; Raimondi, M. J. Phys. Chem. 1995, 99, 10186.
5. (a) Binkley, J. S.; Pople, J. A.; Hehre, W. F. J Am. Chem. Soc. 1980, 102, 939.
6. (b) Pietro, W. J.; Francl, M. M.; Hehre, W. J.; DeFrees, D. J.; Pople, J. A.; Binkley, J. S. J. Am. Chem. Soc. 1982, 104, 5039.
7. (c) Gordon, M. S.; Binkley, J. S.; Pople, J. A.; Pietro, W. J.; Hehre, W. J. J. Am. Chem. Soc. 1982, 104, 2797.
8. (d) Dobbs, K. D.; Hehre, W. J. J. Comput. Chem. 1986, 7, 359.
9. Frisch, M. J.; Trucks, G. W.; Head-Gordon, M.; Gill, P. M. W.; Wong M. W.; Foresman, J. B.; Johnson, B. G.; Schlegel, H. B.; Robb, M. A.; Replogle, E. S.; Comperts, R.; Andreas, J. L.; Raghavachari, K.; Binkley J. S.; Gonzalez, C.; Martin, R. L.; Fox, D. J.; DeFrees, D. J.; Baker, J.; Stewart, J. J. P.; Pople, J. A. GAUSSIAN 92, Revision A; Gaussian, Inc.; Pittsburgh, PA, 1992.
10. Sandström, J. Dynamic NMR Spectroscopy; Academic: New York, 1982; pp 14-18, 96.
11. Oth, J. F. M. Pure Appl. Chem. 1971, 25, 573.
12. Hrovat, D. A.; Borden, W. T. J. Am. Chem. Soc. 1992, 114, 5879.