Chiral and C2-Symmetrlcal Bis(oxazolinylpyrldine)rhodium( III) Complexes: Effective Catalysts for Asymmetric Hydrosilyiation of Ketones

Organometallics

Volumn 8, Issue 3, 1989, Pages 846-848

  Nishiyama, Hisao ^a   Sakaguchi, Hisao ^a   Nakamura, Takashi ^a   Horihata, Mihoko ^a   Kondo, Manabu ^a   Itoh, Kenji ^a  

^a TOYOHASHI UNIVERSITY OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000487271     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00105a047     Document Type: Article

References (5)

1. Noyori, R.; Ohkuma, T.; Kitamura, M.; Takaya, H.; Sayo, N.; Kumobayashi, H.; Akutagawa, S. J. Am. Chem. Soc. 1987,109, 5856. (b) Kitamura, M.; Ohkuma, T.; Inoue, S.; Sayo, N.; Kumobayashi, H.; Akutagawa, S.; Ohta, T.; Takaya, H.; Noyori, R. J. Am. Chem. Soc. 1988, 110, 629. (c) Corey, E. J.; Bakshi, R. K.; Shibata, S.; Chen, C.-P.; Singh, V. K. J. Am. Chem. Soc. 1987, 109, 7925.
2. Ojima, I.; Kogure, T.; Kumagai, M. J. Org. Chem. 1977, 42,1671. For review, see: Ojima, I.; Hirai, K. In Asymmetric Synthesis; Morrison, J. D., Ed.; Academic Press: New York, 1985; Vol. 5, p 103.
3. Brunner, H.; Becker, R.; Riepl, G. Organometallics 1984, 3, 1354. (b) Brunner, H.; Kürzinger, A. J. Organomet. Chem. 1988,346, 413.
4. D= +37.24° (c = 1.02 in EtOH).
5. 2. Brunner, H.; Obermann, U.; Wimmer, P. J. Organomet. Chem. 1986, 316, C1-C3.