Ligand K-edge X-ray absorption spectroscopic studies: Metal-ligand covalency in transition metal tetrathiolates

Inorganica Chimica Acta

Volumn 263, Issue 1-2, 1997, Pages 315-321

  Rose Williams, Kendra ^a   Hedman, Britt ^b   Hodgson, Keith O ^a,b   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

^b SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

Author keywords

Metal ligand covalency; Tetrathiolate complexes; Transition metal complexes; X ray absorption spectroscopy

Indexed keywords

COBALT COMPOUNDS; COPPER COMPOUNDS; ELECTRONIC STRUCTURE; LIGANDS; MANGANESE COMPOUNDS; METAL COMPLEXES; NICKEL COMPOUNDS; SPECTROSCOPIC ANALYSIS; SULFUR; TRANSITION METALS; X RAY ABSORPTION SPECTROSCOPY;

COVALENCIES; MODEL COMPLEXES; PRE-EDGE FEATURES; SITE SYMMETRY; SPECTROSCOPIC STUDIES; TETRATHIOLATE COMPLEXES; TRANSITION-METAL CENTERS; VALENCE ORBITALS;

IRON COMPOUNDS;

EID: 0000485078     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)05663-6     Document Type: Article

References (24)

1. A. Bianconi, in D.C. Koningsberger and R. Prins (eds.), X-Ray Absorption, Wiley, New York, 1988, pp. 573-662.
2. R.G. Shulman, Y. Yafet, P. Eisenberger and W.E. Blumberg, Proc. Natl. Acad. Sci. U.S.A., 73 (1976) 1384-1388.
3. L.S. Kau, D.J. Spira-Solomon, J.E. Penner-Hahn, K.O. Hodgson and E.I. Solomon, J. Am. Chem. Soc., 109 (1987) 6433-6442.
4. A.L. Roe, D.J. Schneider, R.J. Mayer, J.W. Pyrz, J. Widom and L. Que, Jr., J. Am. Chem. Soc., 106 (1984) 1676-1681.
5. T.E. Westre, P. Kennepohl, J.G. DeWitt, B. Hedman, K.O. Hodgson and E.I. Solomon, J. Am. Chem. Soc., (1997) in press.
6. M.K. Eidsness, R.J. Sullivan and R.A. Scott, in J.R. Lancaster (ed.), Bioinorganic Chemistry of Nickel, VCH, Florida, 1988, pp. 73-92.
7. S.D. Conradson, B.K. Burgess, W.E. Newton, J.W. McDonald, J.R. Rubinson, S.F. Gheller, L.E. Mortenson, M.W.W. Adams, P.K. Mascharack, W.A. Armstrong, R.H. Holm and K.O. Hodgson, J. Am. Chem. Soc., 107 (1985) 7935-7940.
8. B. Hedman, K.O. Hodgson and E.I. Solomon, J. Am. Chem. Soc., 112 (1990) 1643-1645.
9. S.E. Shadle, J.E. Penner-Hahn, H.J. Schugar, B. Hedman, K.O. Hodgson and E.I. Solomon, J. Am. Chem. Soc., 115 (1993) 767-776.
10. S.E. Shadle, B. Hedman, K.O. Hodgson and E.I. Solomon, Inorg. Chem., 33 (1994) 4235-4244.
11. K. Rose Williams, D.R. Gamelin, L.B. LaCroix, R.P. Houser, W.B. Tolman, T.C. Mulder, S. de Vries, B. Hedman, K.O. Hodgson and E.I. Solomon, J. Am. Chem. Soc., 119 (1997) 613-614.
12. S.E. Shadle, B. Hedman, K.O. Hodgson and E.I. Solomon, J. Am. Chem. Soc., 117 (1995) 2259-2272.
13. A. Silver, S.A. Koch and M. Millar, Inorg. Chim. Acta, 205 (1993) 9-14.
14. B. Hedman, P. Frank, S.F. Gheller, A.L. Roe, W.E. Newton and K.O. Hodgson, J. Am. Chem. Soc., 110 (1988) 3798-3805.
15. F.W. Lytle, R.B. Greegor, D.R. Sandstrom, E.C. Marques, J. Wong, C.L. Spiro, G.P. Huffman and F.E. Huggins, Nucl. Instrum. Meth. Phys. Res., 226 (1984) 542-548.
16. E.A. Stern and S.M. Heald, Rev. Sci. Instrum., 50 (1979) 1579-1582.
17. B.S. Garbow, K.E. Hillstrom and J.J. More, Program, Argonne National Laboratory.
18. B.K. Agarwal, X-ray Spectroscopy, Springer, Berlin, 1979.
19. T.A. Tyson, A.L. Roe, P. Frank, K.O. Hodgson and B. Hedman, Phys. Rev. B, 39A (1989) 6305-6315.
20. F.W. Lytle, in H. Winick, D. Xian, M.-H. Ye and T. Huang (eds.), Applications of Synchrotron Radiation, Gordon and Breach, New York, 1989, pp. 135-223.
21. M.S. Gebhard, J.C. Deaton, S.A. Koch, M. Millar and E.I. Solomon, J. Am. Chem. Soc., 112 (1990) 2217-2231.
22. J.S. Griffith, The Irreducible Tensor Method for Molecular Symmetry Groups, Prentice-Hall, Englewood Cliffs, NJ, 1962.
23. S.B. Piepho and P.N. Schatz, Group Theory in Spectroscopy, Wiley, New York, 1983.
24. C.J. Ballhausen and H.B. Gray, Molecular Orbital Theory, Benjamin, New York, 1964.