Complete retention of Z geometry in allylic substitution catalyzed by an iridium complex

Organic Letters

Volumn 1, Issue 2, 1999, Pages 265-267

  Takeuchi, Ryo ^a   Shiga, Norihito ^a  

^a YOKOHAMA CITY UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000483687     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol990033n     Document Type: Article

References (23)

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3. (b) Reference 1, p 175.
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19. For Pd complex catalyzed allylic amination, see: (a) Åkermark, B.; Åkermark, G.; Hegedus, L. S.; Zetterberg, K. J. Am. Chem. Soc. 1981, 103, 3037.
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21. 6): δ 5.12 (dd, J = 17.2, 2.2 Hz, 1H), 5.21 (dd, J = 10.3, 2.2 Hz, 1H), 5.83 (ddd, J = 17.2, 10.3, 6.9 Hz, 1H).
22. Cone angles of secondary amines are larger than those of primary amines; see: Seligson, A. L.; Trogler, W. C. J. Am. Chem. Soc. 1991, 113, 2520.
23. See reference 8a and references therein.