Reaction of N-trimethylsilylmethyliminodithio-carbonate with carbonyl compounds: Synthetic equivalent of alkylthionitrile ylide

Heterocycles

Volumn 45, Issue 10, 1997, Pages 1913-1919

  Oba, Makoto ^a   Yoshihara, Masahiro ^a   Nagatsuka, Jun ^a   Nishiyama, Kozaburo ^a  

^a TOKAI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000482715     PISSN: 03855414     EISSN: None     Source Type: Journal    
DOI: 10.3987/com-97-7915     Document Type: Article

References (20)

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16. A prolonged reaction time resulted in the formation of complex reaction mixture.
17. In the addition reaction of ethanol toward the isothiocyanate (1), bis(tributyltin) oxide (BTO) was found to be the most effective promoter among the bases tested.
18. In this case, CsF was not effective.
19. Long standing of the reaction mixture in silica gel resulted in the decomposition of the product.
20. O. Tsuge, S. Kanemasa, and K. Matsuda, J. Org. Chem., 1984, 49, 2688.