The first examples of intermolecular weak (agostic) γ-methyl-metal interactions in organolanthanide complexes: The synthesis and X-ray structures of [{Yb(η-CP″)2}∞.] and [{Eu(η-CP″)2}∞] [CP″ C5H3(SiMe3)2-1,3]

Journal of Organometallic Chemistry

Volumn 437, Issue 1-2, 1992, Pages 177-189

  Hitchcock, Peter B ^a   Howard, Judith A K ^b   Lappert, Michael F ^a   Prashar, Sanjiv ^a  

^a UNIVERSITY OF SUSSEX   (United Kingdom)

^b DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000482641     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(92)83442-K     Document Type: Article

References (47)

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2. X-Ray crystallographic determination of the structure of bis(methyl-cyclopentadienyl)ytterbium tetrahydrofuranate and its ready formation by four new routes
3. Divalent lanthanide chemistry. Bis (pentamethylcyclopentadienyl) europium(II) and -ytterbium(II) derivatives: crystal structure of bis (pentamethylcyclopentadienyl) (tetrahydrofuran ytterbium(II) -hemitoluene at 176 K
4. Samarium(II) dicyclopentadienide 1-tetrahydrofuranate
5. Reaction of (C5Me5)2Yb with fluorocarbons: formation of (C5Me5)4Yb2(�-F) by intermolecular C?F activation
6. Bis[Bis(Trimethylsilyl)Amido]Bis(Diethyl Ether)Ytterbium and (Diethyl Ether)Bis(η5-Pentamethylcyclopentadienyl)Ytterbium
7. An empirical method for correcting diffractometer data for absorption effects
8. Solid state structure of bis(pentamethylcyclopentadienyl)barium, (Me5C5)2Ba; the first X-ray crystal structure of an organobarium complex
9. Crystal structure of bis(pentamethylcyclopentadienyl)bis(pyridine)ytterbium(II)
10. X-Ray crystal structures of bis(cyclopentadienyl)tin and bis(pentamethylcyclopentadienyl)lead
11. Sequential Lithiation and Silylation of Stannocene
12. Bis(pentamethylcyclopentadienyl)germanium und -zinn sowie (Pentamethylcyclopentadienyl)germanium- und -zinn-Kationen: Synthese, Struktur und Bindungsverhältnisse
13. Ion model and equilibrium configuration of the gaseous alkaline-earth dihalides
14. The first example of an intermolecular weak (agostic)?-methyl-metal interaction: the low temperature single crystal X-ray and neutron diffraction structure of (MgR2)?[R = CH(SiMe3)2]
15. Synthesis and structural characterisation of the first neutral homoleptic lanthanide metal(III) alkyls: [LnR3][Ln = La or Sm, R = CH(SiMe3)2]