Study of cis-Tetraammineruthenium(II) Chemistry with Linear Dienes

Inorganic Chemistry

Volumn 35, Issue 9, 1996, Pages 2692-2694

  Sugaya, Toshihiro ^a   Tomita, Atsuko ^a   Sago, Hiromitu ^a   Sano, Mitsuru ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000474761     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950427k     Document Type: Article

References (18)

1. Sugaya, T., Sano, M. Inorg. Chem 1993, 32, 5878.
2. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 5th ed.; John Wiley and Sons, Inc.: New York, 1988; p 1152.
3. Ernst, R. D.; Melendez, E.; Stahl, L.; Ziegler, M. L. Organometallics 1991, 10, 3635.
4. Nickel, T.; Porschke, K.; Goddard, R.; Kruger, C. Inorg. Chem. 1992, 31, 4428.
5. SIR. Altomare, A.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.; Burla, M. C.; Polidori, G.; Camalli, M. J. Appl. Crystallogr. 1994, 27, 435. The least-squares program: Mallinson, P. R.; Muir, K. W. J. Appl. Crystallogr. 1985, 18, 51.
6. SIR. Altomare, A.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.; Burla, M. C.; Polidori, G.; Camalli, M. J. Appl. Crystallogr. 1994, 27, 435. The least-squares program: Mallinson, P. R.; Muir, K. W. J. Appl. Crystallogr. 1985, 18, 51.
7. Any tetragonal space groups tetragonal are omitted by the reflection data and the extinction rule.
8. An anisotropical refinement for all non-hydrogen atoms gives very low thermal parameters for the N(1) atom, indicating possible disorder.
9. The distance of the end C - end C bond in s-trans-butadiene is calculated to be 3.62 Å for cis-Ru(acac)2(2,4-dimehyl-1,3-pentadiene). In the case of s-cis-butadiene with the same bond lengthes and bond angles as cis-Ru(acac)2(2,4-dimethyl-1,3-pentadiene), the end C-end C distance can be 2.98 Å. Our unpublished structural data for cis-Ru(acac)2(1,3-butadiene) shows the s-trans-butadiene with 3,45 Å for the end C - end C distance.
10. (a) Erker, G., Kruger, C.; Muller, G. Adv. Organomet. Chem. 1985, 24, 1.
11. (b) Yasuda, H.; Nakamura, A. Angew. Chem., Int. Ed. Engl. 1987, 20, 723.
12. (c) Hunter, A. D.; Legzdins, P., Einstein, F. W. B.; Willis, A. C.; Bursten, B. E.; Gatter, M. G. J. Am. Chem. Soc. 1986, 108, 3843.
13. (d) Melendez, E.; Arif, A. M.; Rheingold, A. L.; Ernst, R. D. J. Amer. Chem. Soc. 1988, 110, 8703.
14. Other ruthenium(II) trans-diene compounds have been reported. (a) Fagan, P. J.; Mahoney, W. A.; Calabrese, J. C.; Williams, I. D. Organometallics 1990, 9, 1843. (b) Benyunes, S. A.; Green, M.; Grimshire, M. J. Organometallics 1989, 8, 2268. (c) Benyunes, S. A.; Day, J. P.; Green, M.; Al-Saadoon, A. W.; Waring, T. L. Angew. Chem., Int. Ed. Engl 1990, 29, 1416.
15. Other ruthenium(II) trans-diene compounds have been reported. (a) Fagan, P. J.; Mahoney, W. A.; Calabrese, J. C.; Williams, I. D. Organometallics 1990, 9, 1843. (b) Benyunes, S. A.; Green, M.; Grimshire, M. J. Organometallics 1989, 8, 2268. (c) Benyunes, S. A.; Day, J. P.; Green, M.; Al-Saadoon, A. W.; Waring, T. L. Angew. Chem., Int. Ed. Engl 1990, 29, 1416.
16. Other ruthenium(II) trans-diene compounds have been reported. (a) Fagan, P. J.; Mahoney, W. A.; Calabrese, J. C.; Williams, I. D. Organometallics 1990, 9, 1843. (b) Benyunes, S. A.; Green, M.; Grimshire, M. J. Organometallics 1989, 8, 2268. (c) Benyunes, S. A.; Day, J. P.; Green, M.; Al-Saadoon, A. W.; Waring, T. L. Angew. Chem., Int. Ed. Engl 1990, 29, 1416.
17. Takemoto, M.; Tomita, A.; Sano, M. To be published.
18. 5 symmetries are defined.