Manganese and cesium derivatives of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C. Crystal structures of Li(THF)2.75(Et2O)0.25(μ-Cl)-MnC(SiMe 3)2SiMe2CH2CH2Me 2Si(Me3Si)2C

Organometallics

Volumn 19, Issue 6, 2000, Pages 1190-1193

  Eaborn, Colin ^a   Hitchcock, Peter B ^a   Smith, J David ^a   Zhang, Suobo ^a   Clegg, William ^b   Izod, Keith ^b   O'Shaughnessy, Paul ^b  

^a UNIVERSITY OF SUSSEX   (United Kingdom)

^b NEWCASTLE UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000473666     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om991020g     Document Type: Article

References (32)

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5. For a review see: Girolami, G. S.; Morris, R. J. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K., Vol. 6, 1995; p 127.
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8. Cahiez, G.; Laboue, B. Tetrahedron Lett. 1992, 33, 4439. Cahiez, G.; Chavant, P.-Y.; Metais, E. Tetrahedron Lett. 1992, 33, 5245. Cahiez, G.; Alami. M. Tetrahedron 1989, 45, 4163.
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23. This value is given in a compilation published by VCH, Weinheim, in 1991, but in view of the very few Cs-C bond lengths that have been measured, it is not clear how it was derived.
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