Diffusion and structure in dilute aqueous alcohol solutions: Evidence for the effects of large apolar solutes on water

Journal of Physical Chemistry B

Volumn 102, Issue 44, 1998, Pages 8874-8879

  Harris, Kenneth R ^a   Newitt, Paula J ^a  

^a UNIVERSITY OF NEW SOUTH WALES   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000473599     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9820370     Document Type: Article

References (24)

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10. Woznyj, M. Thesis, University of Regensburg, Germany, 1985. See also Lang, E. W.; Lüdemann, H.-D. in High-Pressure NMR; Jonas, J., Ed.; Springer-Verlag: Berlin, 1991; p 129.
11. Intra-diffusion refers to the thermal motion of a component of a mixture and is differentiated from inter-diffusion due to mixing caused by a concentration difference; self-diffusion refers to the special case of intra-diffusion for a pure substance. See Albright, J. G.; Mills, R. J. Phys. Chem. 1965, 69, 3120 and Tyrrell, H. J. V; Harris, K. R. Diffusion in Liquids; Butterworth: London, 1984; pp 4, 279 ff, and 318 ff. Both intra- and self-diffusion coefficients are obtained from experimental tracer diffusion coefficients using either isotopic (often radioisotopic) or nuclear spin labeling (in NMR spin-echo measurements). Sometimes corrections for mass or moment of inertia effects are needed to obtain intra-diffusion coefficients from tracer data. As we are interested in the relative effect of pressure, no such corrections have been applied in this study.
12. Intra-diffusion refers to the thermal motion of a component of a mixture and is differentiated from inter-diffusion due to mixing caused by a concentration difference; self-diffusion refers to the special case of intra-diffusion for a pure substance. See Albright, J. G.; Mills, R. J. Phys. Chem. 1965, 69, 3120 and Tyrrell, H. J. V; Harris, K. R. Diffusion in Liquids; Butterworth: London, 1984; pp 4, 279 ff, and 318 ff. Both intra- and self-diffusion coefficients are obtained from experimental tracer diffusion coefficients using either isotopic (often radioisotopic) or nuclear spin labeling (in NMR spin-echo measurements). Sometimes corrections for mass or moment of inertia effects are needed to obtain intra-diffusion coefficients from tracer data. As we are interested in the relative effect of pressure, no such corrections have been applied in this study.
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