High-yield syntheses, under mild conditions, of various neutral and anionic ruthenium and osmium carbonyl clusters by controlled reduction in ethylene glycol of [M(CO)3Cl2]2 or MCl3 (M=Ru, Os) in the presence of Na2CO3 or K2CO3

Journal of Organometallic Chemistry

Volumn 580, Issue 1, 1999, Pages 117-127

  Roveda, Carmen ^a   Cariati, Elena ^a   Lucenti, Elena ^a   Roberto, Dominique ^a  

^a Dipartimento di Chimica Inorganica   (Italy)

Author keywords

Osmium carbonyl clusters synthesis; Osmium trichloride reductive carbonylation; Ruthenium carbonyl clusters synthesis; Ruthenium trichloride reductive carbonylation

Indexed keywords

EID: 0000471923     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)01133-4     Document Type: Article

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