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Volumn 23, Issue 27, 1982, Pages 2719-2722

Reductive ring openings of allyl-alcohol epoxides

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Indexed keywords


EID: 0000459188     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)87440-7     Document Type: Article
Times cited : (220)

References (25)
  • 8
    • 84914219483 scopus 로고    scopus 로고
    • Y. Kishi, S. Hatakeyama and M.D. Lewis, Pure Appl. Chem., in press
  • 14
  • 16
    • 84914219482 scopus 로고    scopus 로고
    • Satisfactory spectroscopic data were obtained for all new compounds described in this paper.
  • 17
    • 84914219481 scopus 로고    scopus 로고
    • The ratio of the two possible regioisomers was greater than 20:1 (NMR).
  • 18
    • 84914219480 scopus 로고    scopus 로고
    • In connection with other research in our laboratories, we have found numerous examples which support this statement.
  • 19
    • 84914219479 scopus 로고    scopus 로고
    • See footnote 7 of the second paper quoted under reference 4.
  • 20
    • 0010640653 scopus 로고
    • .alpha.-Methoxy-.alpha.-trifluoromethylphenylacetic acid, a versatile reagent for the determination of enantiomeric composition of alcohols and amines
    • Optical purity of 14 was examined by H-HMR and F-NMR analyses of its MTPA derivative, prepared according to the Mosher procedure, No minor enantiomer was detected by these analyses.
    • (1969) The Journal of Organic Chemistry , vol.34 , pp. 2543
  • 21
    • 84914219478 scopus 로고    scopus 로고
    • On sodium periodate treatment, the alcohol 3 smoothly yielded an aldehyde, but the alcohols 2, 6, 13, 17 and 19 were recovered unchanged.
  • 22
    • 84914219477 scopus 로고    scopus 로고
    • The ratio was determined by HPLC analysis.
  • 23
    • 84914219476 scopus 로고    scopus 로고
    • This ratio represents the product ratio of 1,3-diol and 1,2-diol.
  • 24
    • 84914219475 scopus 로고    scopus 로고
    • 2/RT) the alcohols 17 and 19 yielded the acetals i and ii, respectively, which were easily separable by silica gel thin layer chromatography.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.