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Further data for (C5(CH3)5)Ir-(P(CH3)3)(CH3)(H) have been obtained for a sample prepared by the independent method described in the reference. IR (C6D6): vIr-H2090 cm-1. Anal. Calcd for C14H28IrP: C, 40.08; H, 6.73. Found: C, 39.68; H, 6.46.
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While not precisely a three-line pattern, the term “virtual triplet” has been used to describe XnAA' ‘X'nspectra. See (b) Tilley, T. D.; Grubbs, R. H.; Bercaw, J. E. Organometallics 1984, 3, 274. (c) Seidler, M. D.; Bergman, R. G. J. Am. Chem. Soc. 1984, 106, 6110.
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(a) Kubas, G. J.; Ryan, R. R.; Swanson, B. I.; Vergamini, P. J.; Wasserman, H. J. J. Am. Chem. Soc. 1984, 106, 451. For free HD the value of jhd= 43.2 Hz (Nageswara Rao, B. D.; Anders, L. R. Phys. Rev. 1965, 140, A112). Since JHX~ 6.51(JDX), 21bthen for free H2, JHH~ 280 Hz. (b) Brevard, C.; Kintzinger, J. P. In “NMR and the Periodic Table”; Harris, R. K., Mann, B. E., Eds.; Academic Press: London, 1978; p 110.
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