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Volumn 107, Issue 12, 1985, Pages 3502-3507

Synthesis of Trimethylphosphine-Substituted (Pentamethylcyclopentadienyl)iridium Hydride Complexes; Protonation and Deprotonation of (C5(CH3)5)Ir(P(CH3)3)H2

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EID: 0000452534     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00298a017     Document Type: Article
Times cited : (100)

References (31)
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    • (a) Janowicz, A. H.; Bergman, R. G. J. Am. Chem. Soc. 1982, 104, 351. (b) Janowicz, A. H.; Bergman, R. G. J. Am. Chem. Soc. 1983, 105, 3929.
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    • Janowicz, A.H.1    Bergman, R.G.2
  • 15
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    • Further data for (C5(CH3)5)Ir-(P(CH3)3)(CH3)(H) have been obtained for a sample prepared by the independent method described in the reference. IR (C6D6): vIr-H2090 cm-1. Anal. Calcd for C14H28IrP: C, 40.08; H, 6.73. Found: C, 39.68; H, 6.46.
    • Wax, M. J.; Stryker, J. M.; Buchanan, J. M.; Kovac, C. A.; Bergman, R. G. J. Am. Chem. Soc. 1984, 106, 1121. Further data for (C5(CH3)5)Ir-(P(CH3)3)(CH3)(H) have been obtained for a sample prepared by the independent method described in the reference. IR (C6D6): vIr-H2090 cm-1. Anal. Calcd for C14H28IrP: C, 40.08; H, 6.73. Found: C, 39.68; H, 6.46.
    • (1984) J. Am. Chem. Soc. , vol.106 , pp. 1121
    • Wax, M.J.1    Stryker, J.M.2    Buchanan, J.M.3    Kovac, C.A.4    Bergman, R.G.5
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    • While not precisely a three-line pattern, the term “virtual triplet” has been used to describe XnAA' ‘X'nspectra. See (b) Tilley, T. D.; Grubbs, R. H.; Bercaw, J. E. Organometallics 1984, 3, 274. (c) Seidler, M. D.; Bergman, R. G. J. Am. Chem. Soc. 1984, 106, 6110.
    • While not precisely a three-line pattern, the term “virtual triplet” has been used to describe XnAA' ‘X'nspectra. See: (a) Harris, R. K. Can. J. Chem. 1964, 42, 2275. (b) Tilley, T. D.; Grubbs, R. H.; Bercaw, J. E. Organometallics 1984, 3, 274. (c) Seidler, M. D.; Bergman, R. G. J. Am. Chem. Soc. 1984, 106, 6110.
    • (1964) Can. J. Chem. , vol.42 , pp. 2275
    • Harris, R.K.1
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    • (b) Green, M. L. H.; Pratt, L.; Wilkinson, G. J. Chem. Soc. 1958, 3916. (c) Rosenblum, M.; Santer, J. O. J. Am. Chem. Soc. 1959, 81, 5517. (d) Davison, A.; McCleverty, J. A.; Wilkinson, G. J. Chem. Soc. 1963, 1133. (e) Fischer, E. O.; Schmidt, M. W. Angew. Chem. 1967, 79, 99. (f) Werner, H.; Kletzin, H. J. Organomet. Chem. 1983, 243, C59. (g) Werner, H.; Wolf, J. Angew. Chem., Int. Ed. Engl. 1982, 21, 296.
    • (a) Wilkinson, G.; Birmingham, J. M. J. Am. Chem. Soc. 1955, 77, 3421. (b) Green, M. L. H.; Pratt, L.; Wilkinson, G. J. Chem. Soc. 1958, 3916. (c) Rosenblum, M.; Santer, J. O. J. Am. Chem. Soc. 1959, 81, 5517. (d) Davison, A.; McCleverty, J. A.; Wilkinson, G. J. Chem. Soc. 1963, 1133. (e) Fischer, E. O.; Schmidt, M. W. Angew. Chem. 1967, 79, 99. (f) Werner, H.; Kletzin, H. J. Organomet. Chem. 1983, 243, C59. (g) Werner, H.; Wolf, J. Angew. Chem., Int. Ed. Engl. 1982, 21, 296.
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    • Wilkinson, G.1    Birmingham, J.M.2
  • 21
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    • For free HD the value of jhd= 43.2 Hz (Nageswara Rao, B. D.; Anders, L. R. Phys. Rev. 1965, 140, A112). Since JHX ~ 6.51(JDX), 21bthen for free H2, JHH~ 280 Hz. (b) Brevard, C.; Kintzinger, J. P. In “NMR and the Periodic Table ”; Harris, R. K., Mann, B. E., Eds.; Academic Press: London, 1978; p 110.
    • (a) Kubas, G. J.; Ryan, R. R.; Swanson, B. I.; Vergamini, P. J.; Wasserman, H. J. J. Am. Chem. Soc. 1984, 106, 451. For free HD the value of jhd= 43.2 Hz (Nageswara Rao, B. D.; Anders, L. R. Phys. Rev. 1965, 140, A112). Since JHX~ 6.51(JDX), 21bthen for free H2, JHH~ 280 Hz. (b) Brevard, C.; Kintzinger, J. P. In “NMR and the Periodic Table”; Harris, R. K., Mann, B. E., Eds.; Academic Press: London, 1978; p 110.
    • (1984) J. Am. Chem. Soc , vol.106 , pp. 451
    • Kubas, G.J.1    Ryan, R.R.2    Swanson, B.I.3    Vergamini, P.J.4    Wasserman, H.J.5
  • 22
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    • Cp2MoH2/(Cp2MoHLi)4 Francis, B. R.; Green, M. L. H.; Luong-Thi, T.; Moser, G. A. J. Chem. Soc., Dalton Trans. 1976, 1339.
    • Cp2MoH2/(Cp2MoHLi)4: D'Aniello, M. J.; Barefield, E. K. J. Organomet. Chem. 1974, 76, C50. Francis, B. R.; Green, M. L. H.; Luong-Thi, T.; Moser, G. A. J. Chem. Soc., Dalton Trans. 1976, 1339.
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    • D'Aniello, M.J.1    Barefield, E.K.2
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    • Cp2WH2/[Cp2WHLi(pmdeta)]x Johnson, M. D.; Shriver, D. F. J. Am. Chem. Soc. 1966, 88, 301. Mink, R. I. Ph.D. Dissertation, University of Illinois, Champaign—Urbana, IL, 1977.
    • Cp2WH2/[Cp2WHLi(pmdeta)]x: Cooper, R. L.; Green, M. L. H.; Moelwyn-Hughes, J. T. J. Organomet. Chem. 1965, 3, 261. Johnson, M. D.; Shriver, D. F. J. Am. Chem. Soc. 1966, 88, 301. Mink, R. I. Ph.D. Dissertation, University of Illinois, Champaign—Urbana, IL, 1977.
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