Redox Behavior of Edge-Shared Bioctahedral [Re2(μ-NCS)2(NCS)8]3- and Its Relationship to the Direct Metal - Metal-Bonded Ion [Re2(NCS)8]2-: A Spectroelectrochemical Study

Inorganic Chemistry

Volumn 35, Issue 7, 1996, Pages 2053-2061

  Clark, Robin J H ^a   Humphrey, David G ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000443250     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9511276     Document Type: Article

References (63)

1. Cotton, F. A.; Walton, R. A. Multiple Bonds Between Metal Atoms, 2nd ed ; Clarendon Press: Oxford, U.K., 1993; pp 62-80.
2. Cotton, F. A.; Frenz, B. A.; Ebner, J. R.; Walton, R. A. J. Chem. Soc., Chem. Commun. 1974, 4-5.
3. Ebner, J. R.; Walton, R. A. Inorg. Chim. Acta 1975, 14, L45-L46.
4. Ebner, J. R.; Walton, R. A. Inorg. Chem. 1975, 14, 1987-1992.
5. Glicksman, H. D.; Walton, R. A. Inorg. Chem. 1978, 17, 3197-3202.
6. Bonati, F.; Cotton, F A. Inorg. Chem. 1967, 6, 1353-1356.
7. Cotton, F. A.; Ucko, D. A. Inorg. Chim. Acta 1972, 6, 161-172.
8. Cotton, F. A.; Dunbar, K. R.; Falvello, L R.; Tomas, M: Walton, R. A. J. Am. Chem. Soc. 1983, 105, 4950-4954.
9. Best, S. P.; Clark, R. J. H., Humphrey, D. G. Inorg. Chem. 1995, 34, 1013-1014.
10. 12 when an X-ray crystall- ographic study revealed an ESBO structure with solely N-bound bridging NCS .
11. Cotton, F. A.; Robinson, W. R.; Walton, R. A.; Whyman, R. Inorg. Chem. 1967, 6, 929-935.
12. Cotton, F. A.; Davison, A.; Ilsley, W. H ; Trop, H. S. Inorg. Chem. 1979, 18, 2719-2723.
13. Barder, T. J.; Cotton, F. A.; Lewis, D.; Schwotzer, W.; Tetrick, S. M.; Walton, R. A. J. Am. Chem. Soc. 1984, 706, 2882-2891.
14. Dunbar, K. R.; Powell, D.; Walton, R. A. J. Chem. Soc., Chem. Commun. 1985, 114-116.
15. Dunbar, K. R.; Powell, D.; Walton, R. A. Inorg. Chem. 1985, 24, 2842-2846.
16. Cotton, F. A.; Dunbar, K. R.; Favello, L. R.; Walton, R. A. Inorg. Chem. 1985, 24, 4180-4187.
17. Cotton, F. A.; Dunbar, K. R. Inorg. Chem. 1987, 26, 1305-1309.
18. Anderson, L. B.; Cotton, F. A.; Dunbar, K. R.; Favello, L. R.; Price. A. C.; Reid, A. H.; Walton, R. A. Inorg. Chem. 1987, 26. 2717-2725.
19. Fanwick, P. E.; Price, A. C.; Walton, R. A. Inorg. Chem. 1987, 26, 3920-3926.
20. Esjornson, D.; Derringer, D. R.; Fanwick, P. E.; Walton, R. A. Inorg. Chem. 1989, 28, 2821-2829.
21. Qi, J.; Fanwick, P E., Walton, R. A. Inorg. Chem. 1990, 29, 457-462.
22. Qi, J.; Fanwick, P. E.; Walton, R. A. Polyhedron 1990, 9, 565-571.
23. Fanwick, P. E.; Qi, J.; Schrier, P. W.; Walton, R. A. Inorg. Chem. 1992, 31, 258-262.
24. Schrier, P. W.; Fanwick, P. E.; Walton, R. A. Inorg. Chem. 1992, 31, 3929-3933.
25. Murray, H. H.; Wei, L.; Sherman, S. E.; Greaney, M. A.; Eriksen, K. A.; Carstensen, B.; Halbert, T. R.; Stiefel, E. I. Inorg. Chem. 1995, 34, 841-853.
26. Barder, T. J.; Walton, R. A. Inorg. Chem. 1982, 21, 2510-2511.
27. Barder, T. J.; Walton, R. A. Inorg. Synth. 1985, 23, 116-118.
28. Best, S. P.; Clark, R. J. H.; Cooney, R. P.; McQueen, R. C. S. Rev: Sci. Instrum. 1987, 58, 2071-2074.
29. Duff, C. M; Heath, G. A Inorg. Chem. 1991, 30, 2528-2535.
30. Cotton, F. A ; Robinson, W. R.; Walton, R. A. Inorg. Chem. 1967, 6, 1257-1258.
31. Hahn, J. E.; Nimry, T.; Robinson, W. R.; Salmon, D. J.; Walton, R. A. J. Chem Soc., Dalton Trans. 1978, 1232-1236.
32. Heath, G. A.; Rapti,. R. G. J. Am. Chem. Soc. 1993, 115, 3768-3769
33. p) of this couple
34. Cotton, F A.; Matusz, M. Inorg. Chem. 1987, 26, 3468-3472.
35. Heath, G. A.; Raptis, R. G. Personal Communication.
36. pa < 1.0.
37. Trop, H. S.; Davison, A.; Jones, A. G. Inorg Chim. Acta 1981, 54, L61.
38. Cotton, F. A. Polyhedron 1987, 6, 667-677.
39. Shaik, S.; Hoffmann, R.; Fisel, C. R.; Summerville, R. H. J. Am. Chem Soc. 1980, 102, 4555-4572.
40. Poli, R.; Torralba, R. C. Inorg. Chim. Acta 1993, 212, 123-134.
41. BEDT-TTF = bis(ethylenedithio)tetrafutvalene.
42. Kepert, C. J.; Day, P. Personal Communication.
43. Gutterman, D. F.; Gray, H. B. Inorg. Chem. 1972, 11, 1727-1733.
44. Gutterman, D F.; Gray, H. B. J. Am. Chem. Soc. 1971, 93, 3364-3371.
45. 37
46. Newman, A. A., Ed. Chemistry and Biochemistry of Thiocyanic Acid and its Derivatives; Academic Press. London, 1975; pp 119-121 and references cited therein.
47. Clark, R. J. H., Humphrey, D. G. Work in progress
48. 4- is not observed.
49. 3-/6- reduction, in all solvents used.
50. Bernstein, S. N ; Dunbar, K. R. Angew. Chem., Int. Ed. Engl. 1992, 31, 1360-1362.
51. Humphrey, D. G. Ph.D. Thesis, The Australian National University, 1992.
52. Heath, G. A.; Humphrey, D. G J. Chem. Soc., Chem. Commun. 1990, 672- 674
53. Bailey, R. A.; Kozak, S. L.; Michelsen, T. W ; Mills, W. N. Coord Chem. Rev. 1971, 6, 407-445.
54. 3- in the presence of potential ligands.
55. This mechanism, or variations thereof, is often used to describe the fluxional exchange of carbonyl groups in polynuclear metal carbonyl compounds. For a general discussion see: Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry. 5th ed ; John Wiley and Sons: New York, 1988; pp 1325-1327.
56. Cotton, F. A.; Walton, R A. Multiple Bonds Between Metal Atoms, 2nd ed.; Clarendon Press- Oxford, U.K., 1993; pp 72-73.
57. Gennett, T.; Geiger, W. E.; Willett, B.; Anson, F. C. J. Electroanal. Chem. 1987, 222, 151-160.
58. Smith, D. A.; Zhuang, B.; Newton, W. E.; McDonald, J. W.; Schultz. F. A. Inorg. Chem. 1977, 16, 2524-2531.
59. Ginsburg, R. E.; Rothrock, R. K ; Finke, R. G.; Collman, J. P.; Dahl, L. F. J. Am. Chem. Soc. 1979, 101, 6550-6562.
60. Collman, J. P.; Rothrock, R. K.; Finke, R. G.; Moore, E. J.; Rose-Munch, F. Inorg. Chem. 1982, 21, 146-150.
61. Heath, G. A.; Raptis, R. G. Inorg. Chem. 1991, 30, 4106-4108.
62. - is located in one of the axial positions collinear with the Re - Re bond: Cotton, F. A.; Shive, L. W , Stults, B. R. Inorg. Chem. 1976, 15, 2239-2244.
63. Nimry, T.; Walton, R. A. inorg. Chem. 1977, 16, 2829-2834.