3-Rhoda-1,2-dioxolanes through Dioxygenation of a Rhodium - Ethene Complex by Air

Angewandte Chemie - International Edition

Volumn 40, Issue 11, 2001, Pages 2106-2108

  Krom, Monique ^a   Coumans, Ruud G E ^a   Smits, Jan M M ^a   Gal, Anton W ^a  

^a RADBOUD UNIVERSITY NIJMEGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000441876     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20010601)40:11<2106::AID-ANIE2106>3.0.CO;2-O     Document Type: Article

References (21)

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9. tpa=tri(2-pyridylmethyl)amine; Metpa=[(6-methyl-2-pyridyl)methyl]di(2-pyridylmethyl)amine.
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12. 6 to precipitate the ethene complex.
13. 3/atom). It was not possible to assign any physically meaningful parameters to the electron densities found in the difference fourier map. Therefore the SQUEEZE procedure was applied to account for these electron densities. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-157414. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
14. +, compared to -0.29 in the 3-platinadioxolane.
15. This range is based on O-O bonds in 48 crystal structures containing a M-O-O-C fragment (M=any metal); 4 outliers were not taken into account.
16. This range is based on O-C bonds in 48 crystal structures containing a M-O-O-C fragment (M=any metal); 9 outliers were not taken into account.
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20. DIRDIF-96. A computer program system for crystal structure determination by Patterson methods and direct methods applied to difference structure factors: P. T. Beurskens, G. Beurskens, W. P. Bosman, R. de Gelder, S. García-Granda, R. O. Gould, R. Israël, J. M. M. Smits, Crystallography Laboratory, University of Nijmegen, The Netherlands, 1996.
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