Rate of cyclization of perfluoro-4-oxa-5-hexenyl radical. Use of tributylgermanium hydride as an effective H-transfer agent for perfluoro-n-alkenyl radicals

Journal of Organic Chemistry

Volumn 61, Issue 14, 1996, Pages 4824-4826

  Dolbier Jr , William R ^a   Rong, Xiao X ^a   Smart, Bruce E ^b   Yang, Zhen Yu ^b  

^a University of Florida ^*  (United States)

^b DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000426803     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo960395y     Document Type: Article

References (21)

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2. Dolbier, W. R., Jr.; Rong, X. X. J. Fluorine Chem. 1995, 72, 235-240.
3. Dolbier, W. R., Jr.; Rong, X. X. Tetrahedron Lett. 1994, 34, 6225-6228.
4. Beckwith, A. L. J.; Glover, S. A. Aust. J. Chem. 1987, 40, 157-173.
5. Beckwith, A. L. J.; Schiesser, C. H. Tetrahedron 1985, 41, 3925-3941.
6. Nakamura, M. et al. in Progress in Pacific Polymer Conference; Anderson, B., Imanishi, Y. Eds.; Springer-Verlag: Berlin-Heidelberg, 1991; p 369.
7. Nakamura, M. et al. US Patent 4,897,457, 1990.
8. Smart, B. E.; Feiring, A. E.; Krespan, C. G.; Yang, Z.-Y.; Hung, M.-H.; Resnick, P. R.; Dolbier, W. R., Jr.; Rong, X. X. Macromol. Symp. 1995, 98, 753-767.
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13. Pan, H.-Q.; Dolbier, W. R., Jr., unpublished results.
14. Pike, P.; Hershberger, S.; Hershberger, J. Tetrahedron Lett. 1985, 26, 6289-6290.
15. Newcomb, M. Tetrahedron 1993, 49, 1151-1176.
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17. All errors are calculated as propagated errors.
18. 10
19. NIST Standard Reference Database 25. NIST Structures and Properties Database and Estimation Program 1991; U.S. Department of Commerce, Gaithersburg, MD.
20. Carlson, D. P. (DuPont), private communication.
21. Stang, P. J.; White, M. R. J. Am. Chem. Soc. 1981, 103, 5429-5433.