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Volumn 113, Issue 8, 1991, Pages 2985-2994

(Tri-tert-butylsilyl)imido Complexes of Titanium: Benzene C–H Activation and Structure of [(tBu3SiNH)Ti]2(µ-NSitBu3)2

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Indexed keywords


EID: 0000422327     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00008a029     Document Type: Article
Times cited : (234)

References (115)
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    • Details of the C–H activation chemistry will be published in due course
    • unpublished results.
    • Details of the C–H activation chemistry will be published in due course: Cummins, C. C.; Schaller, C. P.; Wolczanski, P. T., unpublished results.
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    • For a related deprotonation of a NHSitBu3 group, see
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    • It is possible that amine loss from 4 is responsible for deuteration of the amido hydrogens, instead of eqs 4–7. However, the conditions required for deuteration are much milder than for 1, and efforts directed toward amine elimination to form a bis(imido) derivative have been unsuccessful
    • unpublished results.
    • It is possible that amine loss from 4 is responsible for deuteration of the amido hydrogens, instead of eqs 4–7. However, the conditions required for deuteration are much milder than for 1, and efforts directed toward amine elimination to form a bis(imido) derivative have been unsuccessful. Cummins, C. C.; Wolczanski, P. T., unpublished results.
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