Charge Transport through Chemically Modified Electrodes: A General Analysis for Ion Exchange and Covalently Attached Redox Polymers

Journal of Physical Chemistry B

Volumn 103, Issue 27, 1999, Pages 5687-5697

  Umamaheswari, J ^a   Sangaranarayanan, M V ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY MADRAS   (India)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000421953     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp990481c     Document Type: Article

References (67)

1. (a) Murray, R. W. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1984; Vol. 13.
2. (b) Inzett, G. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1994; Vol.18.
3. Savéant, J. M. J. Electroanal. Chem. 1986, 201, 211.
4. Buck, R. P. J. Phys. Chem. 1988, 92, 4196.
5. Denny, R. A.; Sangaranarayanan, M. V. J. Phys. Chem. B. 1998, 102, 2131.
6. (a) Chidsey, C. E. D.; Murray, R. W. J. Phys. Chem. 1986, 90, 3850.
7. (b) Vorotyntsev, M. A.; Daikhin, L. I.; Levi, M. D. J. Electroanal. Chem. 1994, 364, 37.
8. (a) Srinivasamohan, L.; Sangaranarayanan, M. V. J. Electroanal. Chem. 1992, 323, 375.
9. (b) Blauch, D. N.; Savéant, J. M. J. Phys. Chem. 1993, 97, 6444.
10. (a) Dahms, H. J. Phys. Chem. 1968, 72, 362.
11. (b) Ruff, I.; Friedrich, V. J. J. Phys. Chem. 1971, 75, 3297.
12. (c) Ruff, I.; Friedrich, V. J.; Demeter, K.; Csaillag, K. J. Phys. Chem. 1971, 75, 3303.
13. (d) Ruff, I.; Botár, L. J. Chem. Phys. 1985, 83, 1292.
14. (e) Botár, L.; Ruff, I. Chem. Phys. Lett. 1986, 126, 348.
15. Blauch, D. N.; Savéant, J. M. J. Am. Chem. Soc. 1992, 114, 3323.
16. (a) Martin, C. R.; Dollard, K. A.J. Electroanal. Chem. 1983, 159, 127.
17. (b) Doblhoffer, K.; Lange, R. J. Electroanal. Chem. 1987, 229, 239.
18. (c) Anson, F. C.; Savéant, J. M.; Shigehara, K. J. Am. Chem. Soc. 1983, 105, 1096.
19. (d) Rubinstein, I.; Bard, A. J. J. Am. Chem. Soc. 1981, 103, 5007.
20. (a) Facci, J. S.; Murray, R. W. J. Phys. Chem. 1981, 85, 287
21. (b) Facci, J. S.; Schmehl, R. H.; Murray, R. W. J. Am. Chem. Soc. 1982, 104, 4959.
22. (c) Kuo, K.; Murray, R. W. J. Electroanal. Chem. 1982, 131, 37.
23. (a) Nakazato, K.; Kitahara, K. Prog. Theor. Phys. 1986, 64, 2261.
24. (b) Murch, G. E.; Thorn, R. Philos. Mag. A 1979, 39, 673.
25. (c) Koiwa, M.; Ishioka, S. J. Stat. Phys. 1983, 30, 477.
26. Terrill, R. H.; Shechan, P. E.; Long, V. C.; Washburn, S.; Murray, R. W. J. Phys. Chem. 1994, 98, 5127.
27. -1, δ to be 6 Ȧ,and f as 0.3 in the calculation of apparent diffusion coefficient and ignored the variation of f with the concentration of vacancies.
28. (a) Sharp, M.; Lindholm, B.; Lind, E. J. Electroanal. Chem. 1989, 274, 35.
29. (b) Abraham John, S.; Ramaraj, R. Proc. Indian Acad. Sci. (Chem. Sci.) 1998, 110, 115.
30. Bonhôte, P.; Gogniat, E.; Tingry, S.; Barbé, C.; Vlachopoulos, N.; Lenzmann, F.; Comte, P.; Grätzel, M. J. Phys. Chem. B 1998, 102, 1498.
31. Kumins, C.A.; Kwei, T.K. In Diffusion in Polymers; Crank, J., Dark, G. S., Eds.; Academic Press: New York, 1968; p 107.
32. Lyons, M. E. G. In Annual Reports on the Progress of Chemistry, Section C, Physical Chemistry; The Royal Society of Chemistry: Cambridge, UK, 1990; Vol. 87, p 158.
33. (a) Tsou, Y.; Anson, F. C. J. Phys. Chem. 1985, 89, 3818.
34. (b) Whiteley, L. D.; Martin, C.R. J. Phys. Chem. 1989, 93, 4650.
35. (a) White, H. S.; Leddy, J.; Bard, A.J. J. Am. Chem. Soc. 1982, 104, 4811.
36. (b) Martin, C. R.; Rubinstein, I.; Bard, A. J. J. Am. Chem. Soc. 1982, 104, 4817.
37. (c) Rubinstein, I. J. Electroanal. Chem. 1985, 188, 227.
38. (a) Gurland, J. Trans. Met. Soc. AIME 1966, 236, 642.
39. (b) Malliaris, A.; Turner, D. T. J. Appl. Phys. 1971, 42, 614.
40. (c) Last, B. J.; Thouless, D. J. Phys. Rev. Lett., 1971, 27, 1719.
41. Pourcelly, G.; Oikonomou, A.; Gavach, C.; Hurwitz, H. D. J. Electroanal. Chem. 1990, 287, 43.
42. (a) Marcus, R. A. Annu. Rev. Phys. Chem. 1964, 15, 155.
43. (b) Marcus, R. A. J. Chem. Phys. 1965, 43, 679.
44. (a) Hupp, J. T.; Weaver, M. J. J. Electroanal. Chem. 1983, 152, 1.
45. (b) Sutin, N. Prog. Inorg. Chem. 1983, 30, 441.
46. McManis, G. E.; Nielson, R. M.; Gochev, A.; Weaver, M. J. J. Am. Chem. Soc. 1989, 111, 5533.
47. Mathias, M. F.; Haas, O. J. Phys. Chem. 1993, 97, 9217.
48. Dalton, E. F.; Surridge, N. A.; Jernigan, J. C.; Wilbourn, K. O.; Facci, J. S.; Murray, R. W. Chem. Phys. 1990, 141, 143 and references therein.
49. Jernigan, J. C.; Murray, R. W. J. Phys. Chem. 1987, 91, 2030.
50. (a) Mathias, M. F.; Haas. O. J. Phys. Chem. 1992, 96, 3174.
51. (b) Láng, G.; Inzelt, G. Electrochim. Acta 1999, 44, 2037.
52. Yang, H.; Tianhong, L.; Xue, K., Sun, S.; Lu, G.; Chen, S. J. Electrochem. Soc. 1997, 144, 2302.
53. Elmgren, M.; Lindquist, S.; Henriksson, G.J. Electroanal. Chem. 1992, 341, 257.
54. Giovani, W.; Deronzier, A. J. Electroanal. Chem. 1992, 337, 285.
55. Denny, R. A.; Sangaranarayanan, M. V. J. Phys. Chem. B. 1998, 102, 2138.
56. eq) invariant with potential.
57. Newman, J. S. In Electrochemical Systems; Prentice Hall: Englewood Cliffs NJ, 1973.
58. Denny, R. A.; Sangaranarayanan, M. V. J. Phys. A: Math. Gen. 1998, 31, 7671.
59. (a) He, P.; Chen, X. J. Electroanal. Chem. 1988, 256, 353.
60. (b) Fritsch-Faules, I.; Faulkner, L. R. J. Electroanal. Chem. 1989, 263, 237.
61. Buttry, D. A.; Anson, F. C. J. Am. Chem. Soc. 1983, 105, 685.
62. Denny, R. A.; Sangaranarayanan, M. V. J. Phys. Chem. B. 1998, 102, 8670.
63. -1 which lead to the polymer film concentration of 2.06 M from eq A-4. Thus, we obtain the concentration of vacancy to be 5.6 M using eq A-5.
64. The volume of the redox polymeric film may change as the redox reaction proceeds due to the intake or the expulsion of the counterions depending upon the nature of the electrochemical reaction.
65. 41b albeit without the blocking factor χ.
66. (b) Zhang, L.; Macdonald, D. D. Electrochim. Acta 1988, 43, 679.
67. Savéant, J. M. J. Phys. Chem. 1988, 92, 4526.