Lithiated γ-tosyl-substituted benzylmethallylamine: New γ-amino methallyl sulfone anions in organic synthesis

Journal of Organic Chemistry

Volumn 61, Issue 15, 1996, Pages 5004-5012

  Alonso, Diego A ^a   Falvello, Larry R ^b   Mancheño, Balbino ^c   Nájera, Carmen ^c   Tomás, Milagros ^b  

^a UNIVERSITY OF ALICANTE   (Spain)

^b UNIVERSITY OF ZARAGOZA   (Spain)

^c NONE

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000420517     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9602478     Document Type: Article

References (40)

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15. For the corresponding unsubstituted allyl organolithium compounds derived from methallylamines see: (a) Fitt, J. J.; Gschwend, H. W. J. Org. Chem. 1981, 46, 3349-3352. (b) Barluenga, J.; Fañanás, F. J.; Foubelo, F.; Yus, M. J. Chem. Soc., Chem. Commun. 1988, 1135-1136. (c) Barluenga, J.; González, R.; Fañanás, F. J. Tetrahedron Lett. 1992, 33, 7573-7574. (d) Foubelo, F. Ph.D. Thesis, University of Oviedo, 1989.
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26. 5
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35. 2O content measured gas chromatographically) does not allow the determination of %D content. Thus, calculated %H/D values are corrected considering this fact.
36. Diffractometer control program. For 20g: CAD4-PC, Delft Instruments X-ray Diffraction bv, Delft, The Netherlands, 1993. For 20i: CAD4-PC V 1.5c, Delft Instruments X-ray Diffraction bv, Delft, The Netherlands, 1994.
37. 29 were done on a Hewlett-Packard 715/50 (HP-UX V9.01).
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40. The author has deposited atomic coordinates for 20g,i with the Cambridge Crystallographic Data Centre. The coordinates can be obtained, on request, from the Director, Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK.