cis-iso-Specific polymerization of norbornenes by a unique combination of Cp* and 1,3-butadiene ligands on tantalum: Crystal structures of Cp*(η4-C4H6)Ta(CH2Ph) 2 and Cp*(η4-C4H6)Ta(=CHPh)(PMe 3)

Organometallics

Volumn 15, Issue 10, 1996, Pages 2431-2433

  Mashima, Kazushi ^a   Tanaka, Yoshiyuki ^a   Kaidzu, Michitaka ^a   Nakamura, Akira ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000414640     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960023f     Document Type: Article

References (40)

1. For comprehensive reviews: Ivin, K. J. Olefin Metathesis; Academic Press: New York, 1983. Ivin, K. J.; Saegusa, T. Ring-Opening Polymerization; Elsevier: London, 1984. Dragutan, V.; Balaban, A. T.; Dimonie, M. Olefin Metathesis and Ring Opening Polymerization of Cyclo-Olefins, 2nd ed.; Wiley-Interscience: New York, 1985. Grubbs, R. H.; Tumas, W. Science 1989, 243, 907. Schrock, R. R. Acc. Chem. Res 1990, 23, 158. Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1.
2. For comprehensive reviews: Ivin, K. J. Olefin Metathesis; Academic Press: New York, 1983. Ivin, K. J.; Saegusa, T. Ring-Opening Polymerization; Elsevier: London, 1984. Dragutan, V.; Balaban, A. T.; Dimonie, M. Olefin Metathesis and Ring Opening Polymerization of Cyclo-Olefins, 2nd ed.; Wiley-Interscience: New York, 1985. Grubbs, R. H.; Tumas, W. Science 1989, 243, 907. Schrock, R. R. Acc. Chem. Res 1990, 23, 158. Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1.
3. For comprehensive reviews: Ivin, K. J. Olefin Metathesis; Academic Press: New York, 1983. Ivin, K. J.; Saegusa, T. Ring-Opening Polymerization; Elsevier: London, 1984. Dragutan, V.; Balaban, A. T.; Dimonie, M. Olefin Metathesis and Ring Opening Polymerization of Cyclo-Olefins, 2nd ed.; Wiley-Interscience: New York, 1985. Grubbs, R. H.; Tumas, W. Science 1989, 243, 907. Schrock, R. R. Acc. Chem. Res 1990, 23, 158. Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1.
4. For comprehensive reviews: Ivin, K. J. Olefin Metathesis; Academic Press: New York, 1983. Ivin, K. J.; Saegusa, T. Ring-Opening Polymerization; Elsevier: London, 1984. Dragutan, V.; Balaban, A. T.; Dimonie, M. Olefin Metathesis and Ring Opening Polymerization of Cyclo-Olefins, 2nd ed.; Wiley-Interscience: New York, 1985. Grubbs, R. H.; Tumas, W. Science 1989, 243, 907. Schrock, R. R. Acc. Chem. Res 1990, 23, 158. Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1.
5. For comprehensive reviews: Ivin, K. J. Olefin Metathesis; Academic Press: New York, 1983. Ivin, K. J.; Saegusa, T. Ring-Opening Polymerization; Elsevier: London, 1984. Dragutan, V.; Balaban, A. T.; Dimonie, M. Olefin Metathesis and Ring Opening Polymerization of Cyclo-Olefins, 2nd ed.; Wiley-Interscience: New York, 1985. Grubbs, R. H.; Tumas, W. Science 1989, 243, 907. Schrock, R. R. Acc. Chem. Res 1990, 23, 158. Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1.
6. For comprehensive reviews: Ivin, K. J. Olefin Metathesis; Academic Press: New York, 1983. Ivin, K. J.; Saegusa, T. Ring-Opening Polymerization; Elsevier: London, 1984. Dragutan, V.; Balaban, A. T.; Dimonie, M. Olefin Metathesis and Ring Opening Polymerization of Cyclo-Olefins, 2nd ed.; Wiley-Interscience: New York, 1985. Grubbs, R. H.; Tumas, W. Science 1989, 243, 907. Schrock, R. R. Acc. Chem. Res 1990, 23, 158. Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1.
7. Examples for the ROMP of norbornene by Ta: Wallace, K. C.; Liu, A. H.; Dewan, J. C.; Schrock, R. R. J. Am. Chem. Soc. 1988, 110, 4964. Wallace, K. C.; Schrock, R. R. Macromolecules 1987, 20, 448.
8. Examples for the ROMP of norbornene by Ta: Wallace, K. C.; Liu, A. H.; Dewan, J. C.; Schrock, R. R. J. Am. Chem. Soc. 1988, 110, 4964. Wallace, K. C.; Schrock, R. R. Macromolecules 1987, 20, 448.
9. Bazan, G. C.; Khosravi, E.; Schrock, R. R.; Feast, W. J.; Gibson, V. C.; O'Regan, M. B.; Thomas, J. K.; Davis, W. M. J. Am. Chem. Soc. 1990, 112, 8378.
10. (a) Feast, W. J.; Gibson, V. C.; Marshall, E. L. J. Chem. Soc., Chem. Commun. 1992, 1157.
11. (b) Feast, W. J.; Gibson, V. C.; Ivin, K. J.; Kenwright, A. M.; Khosravi, E. J. Chem. Soc., Chem. Commun. 1994, 1399.
12. McConville, D. H.; Hofmeister, G. E.; Schrock, R. R. J. Am. Chem. Soc. 1993, 115, 4413.
13. O'Dell, R.; McConville, D. H.; Hofmeister, G. E.; Schrock, R. R. J. Am. Chem. Soc. 1994, 116, 3414 and references cited therein.
14. Schrock, R. R.; Lee, J.-K.; O'Dell, R.; Oskam, J. H. Macromolecules 1995, 28, 5933.
15. Nguyen, S. T.; Johnson, L. K.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1992, 114, 3974 and references cited therein.
16. Gilliom, L. R.; Grubbs, R. H. J. Am. Chem. Soc. 1986, 108, 733.
17. Petasis, N. A.; Fu, D.-K. J. Am. Chem. Soc. 1993, 115, 7208 and references cited therein.
18. Mashima, K.; Tanaka, Y.; Nakamura, A. Organometallics 1995, 14, 5642.
19. Mashima, K.; Fujikawa, S.; Tanaka, Y.; Urata, H.; Oshiki, T.; Tanaka, E.; Nakamura, A. Organometallics 1995, 14, 2633.
20. Mashima, K.; Fujikawa, S.; Nakamura, A. J. Am. Chem. Soc. 1993, 115, 10990.
21. Mashima, K.; Fujikawa, S.; Urata, H.; Tanaka, E.; Nakamura, A. J. Chem. Soc., Chem. Commun. 1994, 1623.
22. 17
23. Ivin, K. J.; Laverty, D. T.; Rooney, J. J. Makromol. Chem. 1977, 778, 1545.
24. Grubbs, R. H.; Gilliom, L. R. J. Mol. Catal. 1988, 46, 255.
25. Mashima, K.; Yamanaka, Y.; Fujikawa, S.; Yasuda, H.; Nakamura, A. J. Organomet. Chem. 1992, 428, C5. Yasuda, H.; Tatsumi, K.; Okamoto, T.; Mashima, K.; Lee, K.; Nakamura, A.; Kai, Y.; Kanehisa, N.; Kasai, N. J. Am. Chem. Soc. 1985, 107, 2410.
26. Mashima, K.; Yamanaka, Y.; Fujikawa, S.; Yasuda, H.; Nakamura, A. J. Organomet. Chem. 1992, 428, C5. Yasuda, H.; Tatsumi, K.; Okamoto, T.; Mashima, K.; Lee, K.; Nakamura, A.; Kai, Y.; Kanehisa, N.; Kasai, N. J. Am. Chem. Soc. 1985, 107, 2410.
27. Spectral data for 2-4 are presented in the Supporting Information.
28. w = 0.031.
29. Katz, T. J.; Lee, S. J.; Acton, N. Tetrahedron Lett. 1976, 4247. Katz, T. J.; Acton, N. Tetrahedron Lett. 1976, 4251.
30. Katz, T. J.; Lee, S. J.; Acton, N. Tetrahedron Lett. 1976, 4247. Katz, T. J.; Acton, N. Tetrahedron Lett. 1976, 4251.
31. Hamilton, J. G.; Ivin, K. J.; Rooney, J. J. J. Mol. Catal. 1988, 28, 255.
32. 7
33. Schrock, R. R.; Messerle, L. W.; Wood, C. D.; Guggenberger, L. J. J. Am. Chem. Soc. 1978, 100, 3793.
34. Messerle, L. W.; Jennische, P.; Schrock, R. R.; Stucky, G. J. Am. Chem. Soc. 1980, 102, 6744.
35. w = 0.035.
36. Buijink, J.-K.; Teuben, J. H.; Kooijman, H.; Spek, A. L. Organometallics 1994, 13, 2922.
37. Cockcroft, J. K.; Gibson, V. C.; Howard, J. A. K.; Poole, A. D.; Siemeling, U.; Wilson, C. J. Chem. Soc., Chem. Commun. 1992, 1668.
38. Experimental details are presented in the Supporting Information.
39. Schrock, R. R. J. Am. Chem. Soc. 1976, 98, 5399.
40. Freundlich, J. S.; Schrock, R. R.; Cummins, C. C.; Davis, W. M. J. Am. Chem. Soc. 1994, 116, 6476.