Cobalt-Alkyne Complexes with Diphosphine Ligands as Mechanistic Probes for the Pauson-Khand Reaction

Organometallics

Volumn 18, Issue 19, 1999, Pages 3859-3864

  Derdau, Volker ^a   Laschat, Sabine ^a   Dix, Ina ^a   Jones, Peter G ^a  

^a TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000412339     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990311m     Document Type: Article

References (65)

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2. Reviews: (a) Schore, N. E. Org. React. 1991, 40, 1-90. (b) Pauson, P. L. Tetrahedron 1985, 41, 5855-5860. (c) Jeong, N. In Transition Metals for Organic Synthesis; Bolm, C., Beller, M., Eds.; Wiley-VCH: New York, 1998; p 560-577. (d) Pauson, P. L. In Organometallics in Organic Synthesis; de Meijere, A., tom Dieck, H., Eds.; Springer-Verlag: Berlin, 1987; p 233. (e) Schore, N. E. In Comprehensive Organic Synthesis; Trost, B. M., Ed.; Pergamon Press: Oxford, U.K., 1991; Vol. 5, pp 1037-1074. (f) Schore, N. E. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, U.K., 1995; Vol. 12, pp 703-739. (g) Geis, O.; Schmalz, H.-G. Angew. Chem. 1998, 110, 955-958; Angew. Chem., Int. Ed. Engl. 1998, 37, 911-915.
3. Reviews: (a) Schore, N. E. Org. React. 1991, 40, 1-90. (b) Pauson, P. L. Tetrahedron 1985, 41, 5855-5860. (c) Jeong, N. In Transition Metals for Organic Synthesis; Bolm, C., Beller, M., Eds.; Wiley-VCH: New York, 1998; p 560-577. (d) Pauson, P. L. In Organometallics in Organic Synthesis; de Meijere, A., tom Dieck, H., Eds.; Springer-Verlag: Berlin, 1987; p 233. (e) Schore, N. E. In Comprehensive Organic Synthesis; Trost, B. M., Ed.; Pergamon Press: Oxford, U.K., 1991; Vol. 5, pp 1037-1074. (f) Schore, N. E. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, U.K., 1995; Vol. 12, pp 703-739. (g) Geis, O.; Schmalz, H.-G. Angew. Chem. 1998, 110, 955-958; Angew. Chem., Int. Ed. Engl. 1998, 37, 911-915.
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55. We have deposited atomic coordinates for the structures of 6a and 7 with the Cambridge Crystallographic Data Centre. The coordinates can be obtained on request from the Director, Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, U.K., upon quoting the reference number CCDC 133169/133170.
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61. 3 only inhibits the reaction when it is directly bound to the cobalt center. In addition, it retards the reactivity of the neighboring cobalt center.
62. 18
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